Ambient Temperature Dehydrogenative C (Ar)–H Carbonylative Lactamization of 2-Arylanilines Using DMF as C1-Source

YZ Chen, TH Ding, QQ Li, JP Qu, YB Kang - Organic Letters, 2023 - ACS Publications
The direct dehydrogenative C–H cleaving carbonylative lactamization of 2-arylanilines
promoted by visible light and potassium bases is reported. Solvent DMF acts as the sole …

Construction and Phosphorescence Behavior of S/Se-Heteroaromatics/Phenanthrene-Fused Hetero [9] helicenes

Y Dong, Z Sun, W Xu, Z Ma, S Qiu, C Li, H Wang - Organic Letters, 2023 - ACS Publications
Three S/Se-hetero [9] helicenes were synthesized by an assembly strategy of two building
blocks, phenanthrene and ternary fused S/Se-heteroaromatic ring, and characterized by …

Adsorption and Self-Aggregation of Chiral [5]-Aza [6] helicenes on DNA Architecture: A Molecular Dynamics Study

G Raffaini - The Journal of Physical Chemistry B, 2023 - ACS Publications
Helicenes are an extremely interesting class of conjugated molecules without asymmetric
carbon atoms but with intrinsic chirality. These molecules can interact with double-stranded …

HFIP-promoted halo-carbocyclizations of N-and O-tethered arene–alkene substrates to access all halo (X= Br, I, Cl)-functionalized tetrahydroquinoline and chroman …

PM Shukla, A Bhattacharya, A Pratap… - Organic & …, 2022 - pubs.rsc.org
A new method for the stereoselective metal-, additive-and oxidant-free Friedel–Crafts-type
halo-carbocyclization of N-and O-tethered arene–olefin substrates is reported, involving …

Dibenzyl Isophthalates as Versatile Hosts in Room Temperature Phosphorescence Host-Guest Systems

M Molkenthin, E Hupf, BJ Nachtsheim - Chemical Science, 2025 - pubs.rsc.org
We report a series of dibenzyl isophthalates (DBIs) as novel hosts for room-temperature
phosphorescence (RTP) host-guest systems, achieving RTP quantum yields (QY) of up to …

Resolution of 9, 10-Diketo [7] helicene and Its Use in One-Step Preparation of Helicene-Based D–A–D Push–Pull Systems

M Kos, T Beránek, I Císařová… - The Journal of …, 2024 - ACS Publications
Racemic 9, 10-diketo [7] helicene was successfully separated into enantiomers using a
reversible and stereoselective reaction with 2, 2′-diamino-1, 1′-binaphthalene with …

Modification of optical properties in helicenes via construction of phosphine oxide-based push-pull systems

T Beránek, M Kos, L Váňa, I Císařová, J Sýkora… - Dyes and …, 2023 - Elsevier
Abstract Six [6] helicene based push-pull systems combining three diarylamines as donors
and two phosphine-oxides as acceptors were designed and synthesized in order to modify …

Synthesis of a Blue‐Emissive Azaborathia [9] helicene by Silicon‐Boron Exchange from Unusual Atropisomeric Teraryls

D Volland, J Niedens, PT Geppert… - Angewandte …, 2023 - Wiley Online Library
We report the concise synthesis and chir (optical) properties of an azaborathia [9] helicene
consisting of two thienoazaborole motifs. The key intermediate, a highly congested teraryl …

Structure and photophysical properties of furoquinoline aza-helicenes: Fluorescence enhancement by protonation

RY Balakhonov, EB Gaeva, IS Mekeda, RA Dolotov… - Dyes and …, 2024 - Elsevier
In recent years, the introduction of one or more heteroaromatic rings into a polyaromatic
backbone has attracted growing interest as it allows significant control over optical …

Amide moiety as analogue of double bond in aza-1, 3, 5-hexatriene system: Photochemical synthesis of benzofuro [3, 2-c] isoquinolines

TT Karibov, BV Lichitsky, AN Komogortsev… - Tetrahedron, 2023 - Elsevier
For the first time the possibility of regiospecific photocyclization of 3-amido-2-
arylbenzofurans was demonstrated. Distinctive feature of the studied photoreaction is …