Heavy metal behaviour at mineral-organo interfaces: Mechanisms, modelling and influence factors

C Qu, W Chen, X Hu, P Cai, C Chen, XY Yu… - Environment …, 2019 - Elsevier
The mineral-organo composites control the speciation, mobility and bioavailability of heavy
metals in soils and sediments by surface adsorption and precipitation. The dynamic changes …

Arsenic speciation in solids using X-ray absorption spectroscopy

AL Foster, CS Kim - Reviews in Mineralogy and …, 2014 - pubs.geoscienceworld.org
Synchrotron-based X-ray absorption spectroscopy (XAS) is an in situ, minimallydestructive,
element-specific, molecular-scale structural probe that has been employed to study the …

Redox-active oxygen-containing functional groups in activated carbon facilitate microbial reduction of ferrihydrite

S Wu, G Fang, Y Wang, Y Zheng, C Wang… - Environmental …, 2017 - ACS Publications
Carbonaceous materials are commonly used in agronomic and environmental applications
primarily as geosorbents, but their redox properties that may affect biogeochemical reactions …

Green Rust Formation during Fe(II) Oxidation by the Nitrate-Reducing Acidovorax sp. Strain BoFeN1

C Pantke, M Obst, K Benzerara, G Morin… - … science & technology, 2012 - ACS Publications
Green rust (GR) as highly reactive iron mineral potentially plays a key role for the fate of (in)
organic contaminants, such as chromium or arsenic, and nitroaromatic compounds …

Temperature dependence and coupling of iron and arsenic reduction and release during flooding of a contaminated soil

FA Weber, AF Hofacker, A Voegelin… - … science & technology, 2010 - ACS Publications
Arsenic (As) in soils and sediments is commonly mobilized when anoxic conditions promote
microbial iron (Fe) and As reduction. Recent laboratory studies and field observations have …

XANES Evidence for Rapid Arsenic(III) Oxidation at Magnetite and Ferrihydrite Surfaces by Dissolved O2 via Fe2+-Mediated Reactions

G Ona-Nguema, G Morin, Y Wang… - … science & technology, 2010 - ACS Publications
To reduce the adverse effects of arsenic on humans, various technologies are used to
remove arsenic from groundwater, most relying on As adsorption on Fe-(oxyhydr) oxides …

Co-oxidation of As (III) and Fe (II) by oxygen through complexation between As (III) and Fe (II)/Fe (III) species

W Ding, J Xu, T Chen, C Liu, J Li, F Wu - Water research, 2018 - Elsevier
Previous studies have shown that the oxidation of Fe (II) by molecular oxygen can lead to
the co-oxidation of As (III) at neutral pH. However, the mechanism of As (III) oxidation in the …

New insight into the structure of nanocrystalline ferrihydrite: EXAFS evidence for tetrahedrally coordinated iron (III)

F Maillot, G Morin, Y Wang, D Bonnin… - … et Cosmochimica Acta, 2011 - Elsevier
Ferrihydrite (Fh) is a short-range ordered nanocrystalline iron (III)(oxyhydr) oxide that has
been recognized to play an important role in contaminant sequestration and in iron cycling …

Oxidation state and local structure of plutonium reacted with magnetite, mackinawite, and chukanovite

R Kirsch, D Fellhauer, M Altmaier, V Neck… - … science & technology, 2011 - ACS Publications
Due to their redox reactivity, surface sorption characteristics, and ubiquity as corrosion
products or as minerals in natural sediments, iron (II)-bearing minerals control to a large …

Effects of oxyanions, natural organic matter, and bacterial cell numbers on the bioreduction of lepidocrocite (γ-FeOOH) and the formation of secondary mineralization …

EJ O'Loughlin, CA Gorski, MM Scherer… - Environmental …, 2010 - ACS Publications
Microbial reduction of Fe (III) oxides results in the production of Fe (II) and may lead to the
subsequent formation of Fe (II)-bearing secondary mineralization products including …