Although the first polysarcosine (pSar) synthesis by Wesseley et al. was reported almost a
century ago, it was only recently that pSar gained broader attention and is considered a …

Polypeptoids, a class of peptidomimetic polymers, have emerged at the forefront of
macromolecular and supramolecular science and engineering as the technological …

Polysarcosine (pSar) was one of the first polymers synthesized in a controlled living manner,
but it was only recently when it was reconsidered as a promising alternative for poly …

The interplay between the tumor cells and their microenvironments is as inseparable as the
relationship between “seeds” and “soil.” The tumor microenvironments (TMEs) exacerbate …

Polysarcosine (PSar), a water-soluble polypeptoid, is gifted with biodegradability via the
random ring-opening copolymerization of sarcosine-and alanine-N-thiocarboxyanhydrides …

Water-soluble polypeptides are a class of synthetic polymers with peptide bond frameworks
imitating natural proteins and have broad prospects in biological applications. The …

α-Amino acid N-thiocarboxyanhydrides (NTAs) are promising cyclic monomers to synthesize
polypeptides and polypeptoids via controlled ring-opening polymerizations. Superior to N …

Polyeptoids are a promising class of polypeptide mimetic biopolymers based on N-
substituted glycine backbones. Because of the high designability of their side chains …

Poly (α-amino acid) s, containing amino acid repeat units, are remarkable biomaterials with
similar structures to protein, which are mainly synthesized by solid phase peptide synthesis …

More and more controlled polymerization methodologies have been developed in the last
decades. However, great challenges still remain in chemoselective polymerizations for …