Microstructural and dynamical heterogeneities in ionic liquids

YL Wang, B Li, S Sarman, F Mocci, ZY Lu… - Chemical …, 2020 - ACS Publications
Ionic liquids (ILs) are a special category of molten salts solely composed of ions with varied
molecular symmetry and charge delocalization. The versatility in combining varied cation …

Synchrotron scattering methods for nanomaterials and soft matter research

T Narayanan, O Konovalov - Materials, 2020 - mdpi.com
This article aims to provide an overview of broad range of applications of synchrotron
scattering methods in the investigation of nanoscale materials. These scattering techniques …

Excess spectroscopy and its applications in the study of solution chemistry

Y Zhang, Z Wu, Y Wang, H He, Z Yu - Pure and Applied Chemistry, 2020 - degruyter.com
Abstract Characterization of structural heterogeneity of liquid solutions and the pursuit of its
nature have been challenging tasks to solution chemists. In the last decade, an emerging …

Potential-dependent structure of the ionic layer at the electrode interface of an ionic liquid probed using neutron reflectometry

N Nishi, J Uchiyashiki, Y Ikeda, S Katakura… - The Journal of …, 2019 - ACS Publications
Neutron reflectometry (NR) has been performed at the electrochemical interface between a
Nb film and an ionic liquid, trihexyltetradecylphosphonium tetrakis (pentafluorophenyl) …

Structure and dynamics of confined liquids: challenges and perspectives for the X-ray surface forces apparatus

H Weiss, HW Cheng, J Mars, H Li, C Merola… - Langmuir, 2019 - ACS Publications
The molecular-scale structure and dynamics of confined liquids has increasingly gained
relevance for applications in nanotechnology. Thus, a detailed knowledge of the structure of …

Surface structure evolution in a homologous series of ionic liquids

J Haddad, D Pontoni, BM Murphy… - Proceedings of the …, 2018 - National Acad Sciences
Interfaces of room temperature ionic liquids (RTILs) are important for both applications and
basic science and are therefore intensely studied. However, the evolution of their interface …

Structure and Surface Behavior of Rh Complexes in Ionic Liquids Studied Using Angle-Resolved X-ray Photoelectron Spectroscopy

D Hemmeter, U Paap, F Maier, HP Steinrück - Catalysts, 2023 - mdpi.com
We present an ARXPS study on the surface composition and interfacial behavior of
commercial [Rh (COD) 2][TfO] in [C2C1Im][TfO],[C4C1Im][TfO],[C8C1Im][TfO], and …

Evolution and reversible polarity of multilayering at the ionic liquid/water interface

S Katakura, K Amano, T Sakka, W Bu… - The Journal of …, 2020 - ACS Publications
Highly correlated positioning of ions underlies Coulomb interactions between ions and
electrified interfaces within dense ionic fluids such as biological cells and ionic liquids …

Evaluation of static differential capacitance at the [C 4 mim+][TFSA−]/electrode interface using molecular dynamics simulation combined with electrochemical surface …

S Zhang, N Nishi, S Katakura, T Sakka - Physical Chemistry Chemical …, 2021 - pubs.rsc.org
Molecular dynamic (MD) simulations have been performed for 1-butyl-3-methylimidazolium
bis (trifluoromethanesulfonyl) amide ([C4mim+][TFSA−]), an ionic liquid (IL), on a charged …

Nanostructure in Amphiphile-Based Deep Eutectic Solvents

I Manasi, R Schweins, K Ma, KJ Edler - Langmuir, 2023 - ACS Publications
Deep eutectic solvents (DESs) are an emerging class of modern, often “green” solvents with
unique properties. Recently, a deep eutectic system based on amphiphilic surfactant N-alkyl …