Mononuclear Dysprosium Alkoxide and Aryloxide Single‐Molecule Magnets

VS Parmar, DP Mills… - Chemistry–A European …, 2021 - Wiley Online Library
Recent studies have shown that mononuclear lanthanide (Ln) complexes can be high‐
performing single‐molecule magnets (SMMs). Recently, there has been an influx of …

Lanthanide (III)-based single-ion magnets

A Dey, P Kalita, V Chandrasekhar - ACS omega, 2018 - ACS Publications
Mononuclear lanthanide-based single-ion magnets (SIMs) are known since 2003 with the
discovery of SIM properties in a bis-(phthalocyaninato) lanthanide complex. A recent report …

Synthesis, structure, and zero-field SMM behavior of homometallic Dy2, Dy4, and Dy6 complexes

P Kumar, A Swain, J Acharya, Y Li, V Kumar… - Inorganic …, 2022 - ACS Publications
The synthesis, structure, and magnetic properties of three DyIII complexes of different
nuclearity,[Dy2 (H2L) 2 (NO3)][NO3]· 2H2O· CH3OH (1),[Dy4 (HL) 2 (piv) 4 (OH) 2](2), and …

Azide-coordination in homometallic dinuclear lanthanide (III) complexes containing nonequivalent lanthanide metal ions: zero-field SMM behavior in the dysprosium …

P Kumar, S Biswas, A Swain, J Acharya… - Inorganic …, 2021 - ACS Publications
A series of homometallic dinuclear lanthanide complexes containing nonequivalent
lanthanide metal centers [Ln2 (LH2)(LH)(CH3OH)(N3)]· x MeOH· y H2O [1, Ln= DyIII, x= 0 …

Synthesis, structures and magnetic studies of hexanuclear lanthanide complexes: SMM behavior of the Dy III analogue and MCE properties of the Gd III analogue

P Kumar, P Kalita, MA Palacios, V Kumar… - Dalton …, 2023 - pubs.rsc.org
The synthesis, structure and magnetic properties of homometallic hexanuclear lanthanide
complexes [Ln6 (HL) 4 (tfa) 4 (S) 2]· 2NO3· x H2O· yMeOH (1, Ln= Gd, S= MeOH, x= 0, y= 0; …

Photoresponsive Magnetic Relaxation Behavior of a Highly Stable π···π Interaction-Stacked Framework Based on a DyIII Single-Ion Magnet

XJ Luo, Y Liu, HD Pan, S Peng, ZB Hu… - Crystal Growth & …, 2023 - ACS Publications
Endowing lanthanide single-ion magnets (Ln-SIMs) with high stability and stimulus
responsiveness is of significance for the practical applications of these novel magnetic …

Dinuclear lanthanide–lithium complexes based on fluorinated β-diketonate with acetal group: Magnetism and effect of crystal packing on mechanoluminescence

DN Bazhin, YS Kudyakova, AS Bogomyakov… - Inorganic Chemistry …, 2019 - pubs.rsc.org
The synthesis of novel dinuclear lanthanide complexes with formulas [(LnL3)(LiL)(MeOH)](1–
3) and [(LnL3)(LiL)(H2O)](4–6)(Ln= Eu (III), Tb (III), Dy (III)) based on functionalized lithium β …

Utilization of diamagnetic Zn (II) ion to boost the anisotropic nature of Ln (III) ion in heterodinuclear Zn (II)–Ln (III) single‐molecule magnets

S Roy, P Shukla, R Kumar, SC Sahoo… - Applied …, 2022 - Wiley Online Library
A series of dimetallic ZnII–LnIII compounds of general formulae [LnZn (L) 3 (NO3) 2]·
2CH3OH (LnIII= DyIII (1), TbIII (2), GdIII (3)) was prepared by stepwise reaction of …

Interplay between anisotropy and magnetic exchange to modulate the magnetic relaxation behaviours of phenoxo bridged Dy 2 dimers with axial β-diketonate co …

S Roy, P Shukla, N Ahmed, MH Du, I Tarannum… - Dalton …, 2022 - pubs.rsc.org
A series of Schiff base LH ((E)-2-((pyridin-2-ylmethylene) amino) phenol) supported
phenoxo bridged symmetric [Dy2 (L) 2 (hfac) 4](1),[Dy2 (L) 2 (tfac) 4](2) and asymmetric [Dy2 …

Syntheses, Structures, and Magnetic Properties of Novel [3× 1+ 2× 1] Pentanuclear Zinc (II)-Lanthanide (III) Cocrystal Complexes: Slow Magnetic Relaxation Behavior …

S Roy, J Du, EM Manohar, T Aziz, TK Pal… - Crystal Growth & …, 2023 - ACS Publications
A new family of 3d-4f polynuclear cocrystals [LnZn2L2 (CH3CO2) 4]·[Zn2Cl4L]· H2O [where
LnIII= Gd (1), Tb (2), and Dy (3)] are synthesized by the sequential reaction of a tetradentate …