Understanding ligand-protected noble metal nanoclusters at work

MF Matus, H Häkkinen - Nature Reviews Materials, 2023 - nature.com
Ligand-protected noble metal nanoclusters, commonly termed 'monolayer-protected metal
clusters'(MPCs), comprise a common set of structures with an inorganic core stabilized by an …

Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures

R Jin, G Li, S Sharma, Y Li, X Du - Chemical Reviews, 2020 - ACS Publications
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R Jin - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Recent progress on phase engineering of nanomaterials

Q Yun, Y Ge, Z Shi, J Liu, X Wang, A Zhang… - Chemical …, 2023 - ACS Publications
As a key structural parameter, phase depicts the arrangement of atoms in materials.
Normally, a nanomaterial exists in its thermodynamically stable crystal phase. With the …

Ligand design in ligand‐protected gold nanoclusters

B Zhang, J Chen, Y Cao, OJH Chai, J Xie - Small, 2021 - Wiley Online Library
The design of surface ligands is crucial for ligand‐protected gold nanoclusters (Au NCs).
Besides providing good protection for Au NCs, the surface ligands also play the following …

Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities

R Jin, C Zeng, M Zhou, Y Chen - Chemical reviews, 2016 - ACS Publications
Colloidal nanoparticles are being intensely pursued in current nanoscience research.
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …

Au 25 (SR) 18: the captain of the great nanocluster ship

X Kang, H Chong, M Zhu - Nanoscale, 2018 - pubs.rsc.org
Noble metal nanoclusters are in the intermediate state between discrete atoms and
plasmonic nanoparticles and are of significance due to their atomically accurate structures …

Atomically tailored gold nanoclusters for catalytic application

T Higaki, Y Li, S Zhao, Q Li, S Li, XS Du… - Angewandte …, 2019 - Wiley Online Library
Recent advances in the synthetic chemistry of atomically precise metal nanoclusters (NCs)
have significantly broadened the accessible sizes and structures. Such particles are well …

Three-orders-of-magnitude variation of carrier lifetimes with crystal phase of gold nanoclusters

M Zhou, T Higaki, G Hu, MY Sfeir, Y Chen, D Jiang… - Science, 2019 - science.org
We report a three-orders-of-magnitude variation of carrier lifetimes in exotic crystalline
phases of gold nanoclusters (NCs) in addition to the well-known face-centered cubic …

Ligand effects in catalysis by atomically precise gold nanoclusters

XK Wan, JQ Wang, ZA Nan, QM Wang - Science advances, 2017 - science.org
Atomically precise gold nanoclusters are ideal model catalysts with well-defined
compositions and tunable structures. Determination of the ligand effect on catalysis requires …