Advancements and synthetic strategies in conjugated covalent organic cages

J Li, Y Yang, J Yang, C Huang, X Zhu… - Coordination Chemistry …, 2025 - Elsevier
Conjugated covalent organic cages (cCOCs) are three-dimensional (3D) giant molecules
characterized by π-conjugated skeletons and interconnected multi-windows. Their …

Nanographene-Fused Expanded Carbaporphyrin Tweezers

H He, YJ Lee, Z Zong, N Liu, VM Lynch… - Journal of the …, 2023 - ACS Publications
A nanographene-fused expanded carbaporphyrin (5) and its BF2 complex (6) were
synthesized. Single-crystal X-ray structures revealed that 5 and 6 are connected by two hexa …

Phenanthrene‐Embedded Carbaporphyrinoids and Related Systems: From Ligands to Cages and Molecular Switches

B Szyszko - European Journal of Organic Chemistry, 2022 - Wiley Online Library
This Review discusses the recent developments in the field of synthetic chemistry of PAH–
porphyrin hybrids, emphasizing phenanthrene‐embedded carbaporphyrinoids and related …

Inherently Chiral and Symmetrical Heteroatom-Doped Zigzag-Type Hydrocarbon Belts

XY Wang, XY Zhang, S Tong, QH Guo, ML Tan… - CCS …, 2024 - chinesechemsoc.org
Recent years have witnessed a resurgence of study in hydrocarbon belts due to their
potential applications in carbon nanotechnology. By contrast, heteroatom-embedded zigzag …

Functionalized Hydrocarbon Belts: Synthesis, Structure and Properties

Y Peng, S Tong, Y Zhang… - Angewandte Chemie …, 2023 - Wiley Online Library
Hydrocarbon belts have drawn great attention because of their unique structures and
tantalizing properties. Although a few belts and heteroatom‐doped analogs have been …

Near-infrared II emissive diphenylaminoacridine based on the planarized intramolecular charge transfer mechanism

X Zhao, J Cheng, L Zhang, B Yun, K Yan, B Wu… - Cell Reports Physical …, 2023 - cell.com
Small-molecule fluorophores in the second near-infrared window (NIR-II, 1,000–1,700 nm)
have received widespread attention owing to their great breakthrough in deep-tissue …

Perylene Diimide-Embedded Chiral Carbaporphyrin

HX He, HY Zhou, YH Wang, T Qin, B Liu - Organic Letters, 2024 - ACS Publications
Herein, we report the synthesis of a novel carbaporphyrin incorporating perylene diimide
(PDI) and dipyrromethane units. The twisted plane of the PDI subunits imbues …

Di‐2, 7‐pyrenidecaphyrin (1.1. 0.0. 0.1. 1.0. 0.0) and Its Bis‐Organopalladium Complexes: Synthesis and Chiroptical Properties

K Liang, H Chen, X Wang, T Lu, Z Duan… - Angewandte …, 2023 - Wiley Online Library
A non‐aromatic expanded carbaporphyrinoid, incorporating two built‐in 2, 7‐pyrenylene
moieties was synthesized. The intrinsically labile structure was demonstrated by proton …

Charge delocalization and global aromaticity in a partially fused 12-porphyrin nanoring

SM Kopp, H Gotfredsen, J Hergenhahn… - Chem, 2024 - cell.com
Aromatic and antiaromatic ring currents can reveal global electronic delocalization around
the circumference of π-conjugated macrocycles, although these phenomena are poorly …

Synthesis, Characterization, and Resistive Memory Behaviors of Highly Strained Cyclometalated Platinum (II) Nanohoops

Y Xu, MY Leung, L Yan, Z Chen, P Li… - Journal of the …, 2024 - ACS Publications
Strained carbon nanohoops exhibit attractive photophysical properties due to their unique π-
conjugated structure. However, incorporation of such nanohoops into the pincer ligand of …