Tris [3, 5-bis (trifluoromethyl) phenyl] borane (1, BArF18), has been synthesised on a
practical scale for the first time. According to the Gutmann–Beckett method it is a more …

Dimers and oligomers of alkenes represent a category of compounds that are in great
demand in diverse industrial sectors. Among the developing synthetic methods, the catalysis …

Reactions between zirconocene or hafnocene dichlorides and alkylaluminum activators are
involved in several catalytic reactions. This study describes the products formed in reactions …

This study reports nanocomposite synthesis based on high‐density polyethylene with
carbon nanotubes through in situ polymerization by coordination, and the use of an …

The first example of a formal 1, 3‐B− H bond addition across the M− N≡ N unit of an end‐on
dinitrogen complex has been achieved. The use of Piers' borane HB (C6F5) 2 was essential …

The mechanism of H2 heterolysis by the frustrated Lewis pair of B (C6F5) 3 and P (mes) 3
was investigated by isothermal reaction calorimetry in the temperature range from 30 to 90° …

In order to elucidate the dependence of the structure and reactivity of the bimetallic hydride
intermediates formed in the systems metallocene—organoaluminum compound—activator …

The activity and chemoselectivity of the Cp2ZrCl2-XAlBui2 (X= H, Bui) and [Cp2ZrH2] 2-
ClAlEt2 catalytic systems activated by (Ph3C)[B (C6F5) 4] or B (C6F5) 3 were studied in …

The aluminum analogue of Piers' borane,[HAl (C6F5) 2] 31, is prepared on a gram-scale.
Density functional theory (DFT) calculations reveal 1 has a higher fluoride ion affinity (FIA) …

Being valuable precursors in the production of adhesives, lubricants, and other high-
performance synthetic compounds, alkene dimers and oligomers can be obtained using …