Luminescent radicals

A Mizuno, R Matsuoka, T Mibu, T Kusamoto - Chemical Reviews, 2024 - ACS Publications
Organic radicals are attracting increasing interest as a new class of molecular emitters. They
demonstrate electronic excitation and relaxation dynamics based on their doublet or higher …

Synthesis of BODIPY dyes through postfunctionalization of the boron dipyrromethene core

N Boens, B Verbelen, MJ Ortiz, L Jiao… - Coordination Chemistry …, 2019 - Elsevier
Fluorophores based on the 4-bora-3a, 4a-diaza-s-indacene (aka boron dipyrromethene,
boron dipyrrin, or BODIPY) platform have found diverse applications in different fields of …

A borondifluoride‐complex‐based photothermal agent with an 80% photothermal conversion efficiency for photothermal therapy in the NIR‐II window

Z Jiang, C Zhang, X Wang, M Yan… - Angewandte Chemie …, 2021 - Wiley Online Library
Small organic photothermal agents (SOPTAs) that absorb in the second near‐infrared (NIR‐
II, 1000–1700 nm) window are highly desirable in photothermal therapy for their good …

Near-infrared dyes for two-photon absorption in the short-wavelength infrared: strategies towards optical power limiting

S Pascal, S David, C Andraud, O Maury - Chemical Society Reviews, 2021 - pubs.rsc.org
This work provides an overview of the recent advances in the field of two-photon absorbing
chromophores active in the short-wavelength infrared (SWIR) spectral range. Herein the …

Boron-containing organic diradicaloids: dynamically modulating singlet diradical character by lewis acid–base coordination

J Guo, Y Yang, C Dou, Y Wang - Journal of the American …, 2021 - ACS Publications
Organic diradicaloids have unique open-shell structures and properties and promising
applications in organic electronics and spintronics. Incorporation of heteroatoms is an …

Unique double intramolecular and intermolecular exciton coupling in ethene‐bridged aza‐BODIPY dimers for high‐efficiency near‐infrared photothermal conversion …

X Guo, J Yang, M Li, F Zhang, W Bu, H Li… - Angewandte Chemie …, 2022 - Wiley Online Library
Spatial electronic communications of chromophores are both theoretically and practically
fascinating. Despite intramolecular or intermolecular exciton coupling was observed in …

A Terrylene–Anthraquinone Dyad as a Chromophore for Photothermal Therapy in the NIR-II Window

ZH Wu, M Peng, C Ji, P Kardasis… - Journal of the …, 2023 - ACS Publications
A terrylenedicarboximide–anthraquinone dyad, FTQ, with absorption in the second near-
infrared region (NIR-II) is obtained as a high-performance chromophore for photothermal …

Application of multifunctional BODIPY in photodynamic therapy

W Zhang, A Ahmed, H Cong, S Wang, Y Shen, B Yu - Dyes and Pigments, 2021 - Elsevier
At present, BODIPY and its derivatives are a kind of multifunctional photosensitive organic
dyes, because of their small Stokes shift, strong absorption, narrow absorption and …

From open-shell singlet diradicaloids to polyradicaloids

TY Gopalakrishna, W Zeng, X Lu, J Wu - Chemical Communications, 2018 - pubs.rsc.org
In this Feature Article, we highlight our recent efforts toward stable open-shell singlet
diradicaloids and polyradicaloids. A brief review on the historical works in the area is …

Diradicaloid Boron‐Doped Molecular Carbons Achieved by Pentagon‐Fusion

L Yuan, J Yang, S Qi, Y Liu, X Tian, T Jia… - Angewandte …, 2023 - Wiley Online Library
Molecular carbons (MCs) are molecular cutouts of carbon materials. Doping with
heteroatoms and constructing open‐shell structures are two powerful approaches to achieve …