Iridium(III)-Catalyzed Regioselective B(4)–H Amination of o-Carboranes with Sufilimines

K Park, GU Han, S Yoon, E Lee, HC Noh, K Lee… - Organic …, 2023 - ACS Publications
Iridium (III)-catalyzed regioselective B (4)–H amination is developed from the reaction of o-
carborane acids with sulfilimines without any oxidants under mild conditions, which leads to …

Iridium-Catalyzed Regioselective B(4)-Alkenylation and B(3,5)-Dialkenylation of o-Carboranes

HC Noh, CE Kim, K Lee, D Kim, PH Lee - Organic Letters, 2023 - ACS Publications
Iridium (I)-catalyzed regioselective B (4)-alkenylation has been developed from o-carboranyl
sulfoxonium ylides and alkynes through B (4)–H activation. The sequential B (4)-and B (6) …

Borirenes and Boriranes: Development and Perspectives

J Wang, Q Ye - Chemistry–A European Journal, 2024 - Wiley Online Library
Strained compounds constitute a highly topical area of research in chemistry. Borirene and
borirane both feature a BC2 three‐membered ring. They can be viewed as the structural …

A Pd-catalyzed route to carborane-fused boron heterocycles

M Zhu, P Wang, Z Wu, Y Zhong, L Su, Y Xin… - Chemical …, 2024 - pubs.rsc.org
Due to the expanding applications of icosahedral carboranes in medicinal and materials
chemistry research, their functionalizations have become one of the central themes in boron …

Ruthenium‐Catalyzed Selective B(4)‐H Amidation of o‐Carboranes with Dioxazolones

H Yang, HC Noh, PH Lee - Asian Journal of Organic Chemistry, 2023 - Wiley Online Library
A ruthenium‐catalyzed selective B4 amidation of o‐carboranes with a variety of alkyl‐, aryl‐,
and heteroaryl‐substituted dioxazolones is developed by carboxylic acid‐assisted B (4)‐H …

Rhodium(III)-Catalyzed B(4)-Azo Coupling of o-Carboranes with Aryl Diazonium Tetrafluoroborates

K Lee, S Yoon, HC Noh, D Kim, PH Lee - Organic Letters, 2024 - ACS Publications
Rh (III)-catalyzed B (4)-azo coupling reactions of o-carborane acids with aryl diazonium
tetrafluoroborates have been developed, leading to the regioselective formation of B (4)-azo …

Regiodivergent metal-catalyzed B (4)-and C (1)-selenylation of o-carboranes

K Lee, JL Harper, TH Kim, HC Noh, D Kim… - Chemical …, 2023 - pubs.rsc.org
Regiodivergent transition metal-catalyzed B (4)-and C (1)-selenylation reactions of o-
carboranes have been demonstrated. Namely, Ru (II)-catalysis selectively generated B (4) …

Synthesis of o‐carboranyl‐acyl‐substituted diazo compounds from B(4)‐acylmethyl carboranes and 2‐azido‐1,3‐dimethylimidazolinium hexafluorophosphate

C Maeng, GH Ko, K Lee, HC Noh… - Bulletin of the Korean …, 2023 - Wiley Online Library
Abstract Reaction of B (4)‐acylmethyl o‐carborane with 2‐azido‐1, 3‐dimethylimidazolinium
hexafluorophosphate (ADMP) in the presence of 1, 8‐diazabicyclo [5.4. 0]‐undec‐7‐ene …

Iridium (III)-catalyzed remote B (9)− H alkylation of o-carboranes with nitrile template

PH Lee, K Lee, J Kim, B Yang, D Kim - 2024 - researchsquare.com
Although the directing group assisted ortho-B− H activation reactions of o-carboranes have
been well established during the past decade, the meta-B− H activation reactions are …