Vibrational spectroscopy of ionic liquids

VH Paschoal, LFO Faria, MCC Ribeiro - Chemical reviews, 2017 - ACS Publications
Vibrational spectroscopy has continued use as a powerful tool to characterize ionic liquids
since the literature on room temperature molten salts experienced the rapid increase in …

Relaxation and physical aging in network glasses: a review

M Micoulaut - Reports on Progress in Physics, 2016 - iopscience.iop.org
Recent progress in the description of glassy relaxation and aging are reviewed for the wide
class of network-forming materials such as GeO 2, Ge x Se 1− x, silicates (SiO 2–Na 2 O) or …

Is the fragility of a liquid embedded in the properties of its glass?

T Scopigno, G Ruocco, F Sette, G Monaco - Science, 2003 - science.org
When a liquid is cooled below its melting temperature, it usually crystallizes. However, if the
quenching rate is fast enough, the system may remain in a disordered state, progressively …

Correlation of fragility of supercooled liquids with elastic properties of glasses

VN Novikov, Y Ding, AP Sokolov - … Review E—Statistical, Nonlinear, and Soft …, 2005 - APS
We present a detailed analysis of correlations between fragility and other parameters of
glass-forming systems. The analysis shows the importance of the ratio between the …

Raman scattering study on structural and dynamical features of noncrystalline selenium

SN Yannopoulos, KS Andrikopoulos - The Journal of chemical physics, 2004 - pubs.aip.org
We report on a detailed, temperature-dependent, off-resonant Raman scattering study of
glassy and supercooled selenium. Raman spectra in the frequency regime of the first-order …

[HTML][HTML] Perspective: Searching for simplicity rather than universality in glass-forming liquids

K Niss, T Hecksher - The Journal of chemical physics, 2018 - pubs.aip.org
This article gives an overview of experimental results on dynamics in bulk glass-forming
molecular liquids. Rather than looking for phenomenology that is universal, in the sense that …

A critical evaluation of barium silicate glass network polymerization

BJA Moulton, A Picinin, LD Silva, C Doerenkamp… - Journal of Non …, 2022 - Elsevier
The state of polymerization in barium silicate glasses (xBaO·(1-x) SiO 2, 0.28≤ x≤ 0.45)
has been studied by both experiment (Raman, static and MAS 29 Si NMR spectroscopy) and …

Landscapes and fragilities

G Ruocco, F Sciortino, F Zamponi… - The Journal of …, 2004 - pubs.aip.org
The concept of fragility provides a possibility to rank different supercooled liquids on the
basis of the temperature dependence of dynamic and/or thermodynamic quantities. We …

Glass formation and structure in the MgSiO3–Mg2SiO4 pseudobinary system: From degraded networks to ioniclike glasses

AG Kalampounias, NK Nasikas… - The Journal of …, 2009 - pubs.aip.org
A series of glasses x MgO–(1− x) SiO 2 with compositions from enstatite MgSiO 3 (x= 0.5) to
forsterite Mg 2 SiO 4 (x= 0.667) in mole fraction intervals of x≈ 0.02 have been prepared by …

Raman scattering and the low-frequency vibrational spectrum of glasses

B Schmid, W Schirmacher - Physical review letters, 2008 - APS
We present a theory of low-frequency Raman scattering in glasses, based on the concept
that light couples to the elastic strains via spatially fluctuating elasto-optic (Pockels) …