Pressurized Sample Infusion

GT Thomas, S Donnecke, IC Chagunda… - Chemistry …, 2022 - Wiley Online Library
Pressurized sample infusion (PSI) is a simple and effective means of continuously
introducing a solution to an electrospray ionization mass spectrometry (ESI‐MS) source. It …

Theory meets experiment: Gas-phase chemistry of coinage metals

J Roithová, D Schröder - Coordination Chemistry Reviews, 2009 - Elsevier
The close interaction between experiment and theory is a key motif in contemporary
transition-metal chemistry with mechanistic orientation. As an illustration of this aspect, we …

How sensitive and accurate are routine NMR and MS measurements?

AM Tsedilin, AN Fakhrutdinov, DB Eremin… - Mendeleev …, 2015 - Elsevier
The necessary prerequisites to carry out efficient NMR/MS studies and the important points
required to avoid inconsistent measurements are discussed. A comparative assessment of …

Visible-light-controlled ruthenium-catalyzed olefin metathesis

C Theunissen, MA Ashley, T Rovis - Journal of the American …, 2019 - ACS Publications
Olefin metathesis is now one of the most efficient ways to create new carbon–carbon bonds.
While most efforts focused on the development of ever-more efficient catalysts, a particular …

Going beyond electrospray: mass spectrometric studies of chemical reactions in and on liquids

AJ Ingram, CL Boeser, RN Zare - Chemical science, 2016 - pubs.rsc.org
There has been a burst in the number and variety of available ionization techniques to use
mass spectrometry to monitor chemical reactions in and on liquids. Chemists have gained …

Pressurized sample infusion for the continuous analysis of air-and moisture-sensitive reactions using electrospray ionization mass spectrometry

KL Vikse, MP Woods, JS McIndoe - Organometallics, 2010 - ACS Publications
Air-and moisture-sensitive compounds pose handling difficulties for chemists requiring mass
spectrometric analysis. A simple pressurized sample infusion (PSI) system for electrospray …

The Complex Reactivity of [(salen)Fe]2(μ-O) with HBpin and Its Implications in Catalysis

TM Hood, S Lau, M Diefenbach, L Firmstone… - ACS …, 2023 - ACS Publications
We report a detailed study into the method of precatalyst activation during alkyne
cyclotrimerization. During these studies we have prepared a homologous series of Fe (III)-μ …

Coupling an electrospray ionization mass spectrometer with a glovebox: A straightforward, powerful, and convenient combination for analysis of air-sensitive …

AT Lubben, JS McIndoe, AS Weller - Organometallics, 2008 - ACS Publications
Coupling an Electrospray Ionization Mass Spectrometer with a Glovebox: A Straightforward,
Powerful, and Convenient Combination for Analysis of Air-Sensitive Organometallics …

Room temperature aerobic oxidation of alcohols using CuBr2 with TEMPO and a tetradentate polymer based pyridyl-imine ligand

Z Hu, FM Kerton - Applied Catalysis A: General, 2012 - Elsevier
A series of tetradentate pyridyl-imine terminated Schiff-base ligands has been investigated
for their ability in the catalytic oxidation of alcohols when combined with copper bromide …

Catalyst deactivation processes during 1-hexene polymerization

A Joshi, HS Zijlstra, S Collins, JS McIndoe - ACS Catalysis, 2020 - ACS Publications
The catalyst [Cp2Zr (μ-Me) 2AlMe2]+[B (C6F5) 4]−(1) has been studied by electrospray
ionization mass spectrometry in order to better understand the complexities of catalyst …