Simultaneous control of flexibility and rigidity in pore-space-partitioned metal–organic frameworks

Y Xiao, Y Chen, W Wang, H Yang… - Journal of the …, 2023 - ACS Publications
Flexi-MOFs are typically limited to low-connected (< 9) frameworks. Here we report a
platform-wide approach capable of creating a family of high-connected materials …

Tetranuclear CuII Cluster as the Ten Node Building Unit for the Construction of a Metal–Organic Framework for Efficient C2H2/CO2 Separation

F Xiang, H Zhang, Y Yang, L Li, Z Que… - Angewandte Chemie …, 2023 - Wiley Online Library
Rational design of high nuclear copper cluster‐based metal–organic frameworks has not
been established yet. Herein, we report a novel MOF (FJU‐112) with the ten‐connected …

Cyclobutanedicarboxylate metal–organic frameworks as a platform for dramatic amplification of pore partition effect

W Wang, H Yang, Y Chen, X Bu… - Journal of the American …, 2023 - ACS Publications
Ultrafine tuning of MOF structures at subangstrom or picometer levels can help improve
separation selectivity for gases with subtle differences. However, for MOFs with a large …

Active Sites Decorated Nonpolar Pore‐Based MOF for One‐step Acquisition of C2H4 and Recovery of C3H6

GD Wang, YZ Li, WJ Shi, L Hou, YY Wang… - Angewandte …, 2023 - Wiley Online Library
Herein, a 2‐fold interpenetrated metal‐organic framework (MOF) Zn‐BPZ‐TATB with
accessible N/O active sites in nonpolar pore surfaces was reported for one‐step C2H4 …

Structural crystal engineering for energy: Unleashing the potential of metal-organic frameworks for photocatalytic reduction of carbon dioxide

S Subbareddy, SA Shivamurthy, SB Ravikumar… - Materials Today …, 2024 - Elsevier
Metal-organic frameworks (MOFs) are unique materials with unparalleled potential in
various domains ranging from catalysis to gas storage. The captivating synergy between …

Multi‐Stage Optimization of Pore Size and Shape in Pore‐Space‐Partitioned Metal–Organic Frameworks for Highly Selective and Sensitive Benzene Capture

Y Chen, W Wang, S Alston, Y Xiao… - Angewandte Chemie …, 2024 - Wiley Online Library
Compared to exploratory development of new structure types, pushing the limits of
isoreticular synthesis on a high‐performance MOF platform may have higher probability of …

Multi‐Modular Design of Stable Pore‐Space‐Partitioned Metal–Organic Frameworks for Gas Separation Applications

Y Chen, H Yang, W Wang, X Li, Y Wang, AN Hong… - Small, 2023 - Wiley Online Library
Pore space partition (PSP) is an effective materials design method for developing high‐
performance small‐pore materials for storage and separation of gas molecules. The …

Isoreticular Contraction of Cage-like Metal–Organic Frameworks with Optimized Pore Space for Enhanced C2H2/CO2 and C2H2/C2H4 Separations

L Zhang, T Xiao, X Zeng, J You, Z He… - Journal of the …, 2024 - ACS Publications
The C2H2 separation from CO2 and C2H4 is of great importance yet highly challenging in
the petrochemical industry, owing to their similar physical and chemical properties. Herein …

Highly Stable Fe/Co-TPY-MIL-88(NH2) Metal–Organic Framework (MOF) in Enzymatic Cascade Reactions for Chemiluminescence-Based Detection of Extracellular …

Q Jiang, Y Xiao, AN Hong, Y Shen, Z Li, P Feng… - ACS …, 2023 - ACS Publications
Metal–Organic Frameworks (MOFs) can deliver many advantages when acting as enzyme
mimics to assist with signal amplification in molecular detection: they have abundant active …

Metal-cluster-powered ultramicropore alliance in pore-space-partitioned metal-organic frameworks for benchmark one-step ethylene purification

SY Li, SC Fan, P Zhang, WY Yuan, Y Wang, QG Zhai - Chem, 2024 - cell.com
Ultra-fine structural tuning of metal-organic frameworks (MOFs) using isoreticular chemistry
is helpful in designing ideal gas adsorbents but is extremely challenging. Known strategies …