The bridging azido ligand as a central “player” in high-nuclearity 3d-metal cluster chemistry

A Escuer, J Esteban, SP Perlepes… - Coordination Chemistry …, 2014 - Elsevier
The chemistry of the azido-bridged coordination clusters continues to attract the intense
interest of synthetic inorganic chemists and scientists working in the interdisciplinary field of …

Polynuclear transition metal complexes of metal⋯ metal-bridging compartmental pyrazolate ligands

J Klingele, S Dechert, F Meyer - Coordination Chemistry Reviews, 2009 - Elsevier
The present article reviews the structures and properties of di-, oligo-and polynuclear
transition metal complexes of substituted pyrazolate (pz) ligands with ligating side arms (Dn) …

Azide as a bridging ligand and magnetic coupler in transition metal clusters

A Escuer, G Aromí - European journal of inorganic chemistry, 2006 - Wiley Online Library
The synthesis of transition metal spin‐clusters has become an important sub‐discipline of
coordination chemistry, especially since the discovery of single‐molecule magnets (SMMs) …

Azide chemistry–an inorganic perspective, Part I metal azides: overview, general trends and recent developments

WP Fehlhammer, W Beck - Zeitschrift für anorganische und …, 2013 - Wiley Online Library
Abstract With Sharpless' and Meldal's discovery of the immensely supportive effect that
metal catalysis has on Huisgen's classical 1, 3‐dipolar cycloaddition, azides (RN3)–long …

Diverse structures and magnetism of cobalt (II) and manganese (II) compounds with mixed azido and carboxylato bridges induced by methylpyridinium carboxylates

QX Jia, H Tian, JY Zhang… - Chemistry–A European …, 2011 - Wiley Online Library
Herein we present a systematic study of the structures and magnetic properties of six
coordination compounds with mixed azide and zwitterionic carboxylate ligands,[M (N3) 2 (2 …

A rare phenoxido/acetato/azido bridged trinuclear and an unprecedented phenoxido/azido bridged one-dimensional polynuclear nickel (II) complexes: synthesis …

R Biswas, S Mukherjee, P Kar, A Ghosh - Inorganic Chemistry, 2012 - ACS Publications
The reaction of a tridentate Schiff base ligand HL (2-[(3-dimethylaminopropylimino)-methyl]-
phenol) with Ni (II) acetate or perchlorate salts in the presence of azide as coligand has led …

Synthesis, structures, and magnetism of copper (II) and manganese (II) coordination polymers with azide and pyridylbenzoates

XM Zhang, YQ Wang, Y Song, EQ Gao - Inorganic Chemistry, 2011 - ACS Publications
Three transition-metal coordination polymers with azide and/or carboxylate bridges have
been synthesized from 4-(3-pyridyl) benzoic acid (4, 3-Hpybz) and 4-(4-pyridyl) benzoic acid …

Coordination Versatility of Pyrazole‐Based Ligands towards High‐Nuclearity Transition‐Metal and Rare‐Earth Clusters

M Viciano‐Chumillas, S Tanase… - European Journal of …, 2010 - Wiley Online Library
The synthesis of transition‐metal and rare‐earth clusters has become a very active research
field, mainly because these compounds can behave as molecule‐based magnets. The …

First metal azide complex with isonicotinate as a bridging ligand showing new net topology: hydrothermal synthesis, structure, and magnetic properties

FC Liu, YF Zeng, Jiao, XH Bu, J Ribas… - Inorganic …, 2006 - ACS Publications
A new 3D azido-bridged coordination polymer,[Co1. 5 (N3)(OH)(Isonic)] n (1), has been
synthesized and characterized and its magnetic properties studied. Isonicotinate acts as a …

Antiferro-and Ferromagnetic Interactions in Mn (II), Co (II), and Ni (II) Compounds with Mixed Azide− Carboxylate Bridges

Y Ma, JY Zhang, AL Cheng, Q Sun, EQ Gao… - Inorganic …, 2009 - ACS Publications
A series of transition metal coordination polymers with azide and flexible zwitterionic
dicarboxylate ligands was synthesized and structurally and magnetically characterized …