Synthetic organic electrochemical methods since 2000: on the verge of a renaissance

M Yan, Y Kawamata, PS Baran - Chemical Reviews, 2017 - ACS Publications
Electrochemistry represents one of the most intimate ways of interacting with molecules. This
review discusses advances in synthetic organic electrochemistry since 2000. Enabling …

Electrochemical strategies for C–H functionalization and C–N bond formation

MD Kärkäs - Chemical Society Reviews, 2018 - pubs.rsc.org
Conventional methods for carrying out carbon–hydrogen functionalization and carbon–
nitrogen bond formation are typically conducted at elevated temperatures, and rely on …

[PDF][PDF] A Biologically Inspired Cu I/Topaquinone-Like Co-Catalytic System for the Highly Atom-Economical Aerobic Oxidation of Primary Amines to Imines

M Largeron, MB Fleury - Angewandte Chemie International Edition, 2012 - hal.science
Imines are versatile synthetic intermediates in a variety of organic transformations and are
essential pharmacophores in numerous biologically active compounds.[1] Great progress …

Enantiopure 1, 4-benzoxazines via 1, 2-cyclic sulfamidates. synthesis of levofloxacin

JF Bower, P Szeto, T Gallagher - Organic Letters, 2007 - ACS Publications
1, 2-Cyclic sulfamidates undergo efficient and regiospecific nucleophilic cleavage with 2-
bromophenols (and related anilines and thiophenols), followed by Pd (0)-mediated …

Azobisisobutyronitrile initiated aerobic oxidative transformation of amines: coupling of primary amines and cyanation of tertiary amines

L Liu, Z Wang, X Fu, CH Yan - Organic letters, 2012 - ACS Publications
In the presence of a catalytic amount of radical initiator AIBN, primary amines are oxidatively
coupled to imines and tertiary amines are cyanated to α-aminonitriles. These “metal-free” …

Aerobic catalytic systems inspired by copper amine oxidases: recent developments and synthetic applications

M Largeron - Organic & Biomolecular Chemistry, 2017 - pubs.rsc.org
Recent efforts to design synthetic quinone-based catalysts for the efficient aerobic oxidation
of amines to imines have been inspired by copper amine oxidases (CuAOs), a family of …

Electrochemical N-acylation synthesis of amides under aqueous conditions

F Ke, Y Xu, S Zhu, X Lin, C Lin, S Zhou, H Su - Green Chemistry, 2019 - pubs.rsc.org
An electrochemical N-acylation of carboxylic acids with amines was reported. The
sustainable TBAB electrocatalysis proceeded with excellent chemoselectivity and positional …

Environmentally friendly chemoselective oxidation of primary aliphatic amines by using a biomimetic electrocatalytic system

M Largeron, A Chiaroni… - Chemistry–A European …, 2008 - Wiley Online Library
Environmentally friendly oxidation of primary aliphatic amines to imines has been
successfully achieved, under metal‐free conditions, by the use of diverse electrogenerated o …

Cycloaddition Reactions of Enamines

IV Efimov, DI Zhilyaev, LN Kulikova… - European Journal of …, 2023 - Wiley Online Library
This review includes information for around two last decades on cycloaddition reactions of
enamines with various agents in order to build carbo‐and heterocycles. In addition, the …

Recent advances in the synthesis of benzimidazole derivatives from the oxidative coupling of primary amines

M Largeron, KMH Nguyen - Synthesis, 2018 - thieme-connect.com
Benzimidazole belongs to the top five most commonly used five-membered aromatic
nitrogen heterocycles among US FDA approved pharmaceuticals. Over the last few years, a …