Recent progress in dichalcophosphate coinage metal clusters and superatoms

AV Artem'ev, CW Liu - Chemical Communications, 2023 - pubs.rsc.org
Atomically precise clusters of group 11 metals (Cu, Ag, and Au) attract considerable
attention owing to their remarkable structure and fascinating properties. One of the unique …

Thermally activated delayed fluorescence in luminescent cationic copper (i) complexes

C Sandoval-Pauker, M Santander-Nelli, P Dreyse - RSC advances, 2022 - pubs.rsc.org
In this work, the photophysical characteristics of [Cu (N^ N) 2]+ and [Cu (N^ N)(P^ P)]+
complexes were described. The concept of thermally activated delayed fluorescence (TADF) …

Eight-Electron Superatomic Cu31 Nanocluster with Chiral Kernel and NIR-II Emission

T Jia, ZJ Guan, C Zhang, XZ Zhu, YX Chen… - Journal of the …, 2023 - ACS Publications
Owing to the inherent instability caused by the low Cu (I)/Cu (0) half-cell reduction potential,
Cu (0)-containing copper nanoclusters are quite uncommon in comparison to their Ag and …

Thermal enhancement of luminescence for negative Thermal Expansion in Molecular Materials

L Chen, X Chen, R Ma, K Lin, Q Li… - Journal of the …, 2022 - ACS Publications
Overcoming thermal quenching is an essential issue in the practical application of
luminescent materials. Herein, we found that negative thermal expansion (NTE) can achieve …

Stimulus‐Triggered Formation of an Anion–Cation Exciplex in Copper (I) Complexes as a Mechanism for Mechanochromic Phosphorescence

B Hupp, J Nitsch, T Schmitt… - Angewandte Chemie …, 2018 - Wiley Online Library
The investigation of the mechanisms of mechanochromic luminescence is of fundamental
importance for the development of materials for photonic sensors, data storage, and …

Adaptive coordination-driven supramolecular syntheses toward new polymetallic Cu (I) luminescent assemblies

S Evariste, AM Khalil, ME Moussa… - Journal of the …, 2018 - ACS Publications
A thermally activated delayed fluorescence (TADF) tetrametallic Cu (I) metallacycle A
behaves as a conformationally adaptive preorganized precursor to afford, through …

A new subclass of copper (i) hybrid emitters showing TADF with near-unity quantum yields and a strong solvatochromic effect

AY Baranov, MI Rakhmanova, X Hei… - Chemical …, 2023 - pubs.rsc.org
We introduce here a new subclass of copper (I) hybrid emitters simultaneously containing
[CuxIy] z− anions and Cu+ cations, separated in space by a Janus head ligand. When UV …

Phase dependence and mechanical and thermal ductility of the luminescence properties of tetranuclear Cu (i) metallacycle assemblies stabilized by ditopic organo …

C Lecourt, RU Melero, J Schiller, F Moutier… - Inorganic Chemistry …, 2023 - pubs.rsc.org
A new highly solid-state luminescent dicationic Cu (I) 4 metallacycle A based on a mixed P,
As ligand assembly is reported for the first time. Surprisingly, as compared to a previously …

Crystalline metal‐organic materials with thermally activated delayed fluorescence

Z Han, XY Dong, SQ Zang - Advanced Optical Materials, 2021 - Wiley Online Library
Thermally activated delayed fluorescence (TADF) properties of crystalline metal‐organic
materials, mainly including small‐molecule metal–organic complexes, organic ligand …

New approach toward dual-emissive organic–inorganic hybrids by integrating Mn (II) and Cu (I) emission centers in ionic crystals

AV Artem'ev, MP Davydova, AS Berezin… - … Applied Materials & …, 2022 - ACS Publications
Inorganic–organic hybrid luminescent materials have received great attention for their
potential applications in a wide range of clean/renewable energy-related areas, including …