Biologically Relevant Silver (I)–N‐Heterocyclic Carbene Complexes: Synthesis, Structure, Intramolecular Interactions, and Applications
N‐Heterocyclic carbenes (NHCs) complexed with silver represent new, broad‐spectrum
antimicrobial and anticancer agents, normally with low toxicity profiles, and they provide a …
antimicrobial and anticancer agents, normally with low toxicity profiles, and they provide a …
Group XII metal–N-heterocyclic carbene complexes: synthesis, structural diversity, intramolecular interactions, and applications
S Budagumpi, S Endud - Organometallics, 2013 - ACS Publications
This review covers the different methods for the synthesis of group XII metal–NHC
complexes with five-and six-membered NHC systems that have different N-heterocyclic …
complexes with five-and six-membered NHC systems that have different N-heterocyclic …
Efficient transfer hydrogenation of carbonate salts from glycerol using water-soluble iridium N-heterocyclic carbene catalysts
The transfer hydrogenation of CO2 and carbonates from biomass-derived alcohols, such as
glycerol, to afford formic and lactic acid is a highly attractive path to valorizing two waste …
glycerol, to afford formic and lactic acid is a highly attractive path to valorizing two waste …
Next-generation water-soluble homogeneous catalysts for conversion of glycerol to lactic acid
An attractive method for valorization of glycerol is the catalytic transformation to lactic acid.
By overcoming the solubility challenge associated with known homogeneous catalysts for …
By overcoming the solubility challenge associated with known homogeneous catalysts for …
Selective catalytic oxidation of sugar alcohols to lactic acid
MG Manas, J Campos, LS Sharninghausen, E Lin… - Green chemistry, 2015 - pubs.rsc.org
Sorbitol and xylitol obtained from biomass are considered promising potential sources of
both carbon building blocks and energy. We report the efficient and selective conversion of …
both carbon building blocks and energy. We report the efficient and selective conversion of …
Short metal–metal separations and in vitro anticancer studies of a new dinuclear silver (I)-N-heterocyclic carbene complex of para-xylyl-linked bis-benzimidazolium …
A new benzyl-substituted bis-benzimidazolium derivative featuring a para-xylene spacer (1)
has been prepared. Reaction of 1 with Ag2O in stoichiometric ratio followed by metathesis …
has been prepared. Reaction of 1 with Ag2O in stoichiometric ratio followed by metathesis …
Preparation and characterization of PEPPSI-palladium N-heterocyclic carbene complexes using benzimidazolium salts catalyzed Suzuki–Miyaura cross coupling …
New palladium complexes were efficiently synthesized from the reaction of benzimidazolium
salts 2a–e, potassium carbonate (K2CO3) and palladium chloride (PdCl2) in pyridine (for 3a …
salts 2a–e, potassium carbonate (K2CO3) and palladium chloride (PdCl2) in pyridine (for 3a …
Topology control in nitrile-functionalized silver (I)–N-heterocyclic carbene complexes: synthesis, molecular structures, and in vitro anticancer studies
A series of nitrile-functionalized N-heterocyclic carbene (NHC) proligands based on N-
methyl-N′-benzonitrile and N, N′-dibenzonitrile imidazolium salts, 1–4, has been …
methyl-N′-benzonitrile and N, N′-dibenzonitrile imidazolium salts, 1–4, has been …
Synthesis, crystal structures, characterization and biological studies of nitrile-functionalized silver (I) N-heterocyclic carbene complexes
RA Haque, SY Choo, S Budagumpi, AAA Abdullah… - Inorganica Chimica …, 2015 - Elsevier
The synthesis of a series of silver (I) complexes (3a–d),[1-(2′/3′-methylbenzyl)-3-(2 ″/3
″-benzonitrile) benzimidazol-2-ylidenesilver (I)] PF 6, of nitrile-functionalized N-heterocyclic …
″-benzonitrile) benzimidazol-2-ylidenesilver (I)] PF 6, of nitrile-functionalized N-heterocyclic …
Synthesis, crystal structures, and in vitro anticancer properties of new N-heterocyclic carbene (NHC) silver (I)-and gold (I)/(III)-complexes: a rare example of silver (I) …
A series of cationic, linearly coordinated silver (I)–(4–6) and gold (I)/(III)–NHC (NHC= N-
heterocyclic carbene)(7–9) complexes of (benz) imidazol-2-ylidene ligands was prepared …
heterocyclic carbene)(7–9) complexes of (benz) imidazol-2-ylidene ligands was prepared …