Organic molecules in interstellar space: Latest advances

M Guélin, J Cernicharo - Frontiers in Astronomy and Space Sciences, 2022 - frontiersin.org
Although first considered as too diluted for the formation of molecules in-situ and too harsh
an environment for their survival, the interstellar medium has turned out to host a rich palette …

Discovery of benzyne, o-C6H4, in TMC-1 with the QUIJOTE line survey

J Cernicharo, M Agúndez, RI Kaiser… - Astronomy & …, 2021 - aanda.org
We report the detection, for the first time in space, of a new non-functionalised hydrocarbon
cycle in the direction of TMC-1: oC 6 H 4 (ortho-benzyne). We derive a column density for …

2021 census of interstellar, circumstellar, extragalactic, protoplanetary disk, and exoplanetary molecules

BA McGuire - The Astrophysical Journal Supplement Series, 2022 - iopscience.iop.org
To date, 241 individual molecular species, composed of 19 different elements, have been
detected in the interstellar and circumstellar medium by astronomical observations. These …

The mystery of unidentified infrared emission bands

S Kwok - Astrophysics and Space Science, 2022 - Springer
A family of unidentified infrared emission (UIE) bands has been observed throughout the
Universe. The current observed spectral properties of the UIE bands are summarized. These …

Efficient stabilization of cyanonaphthalene by fast radiative cooling and implications for the resilience of small PAHs in interstellar clouds

MH Stockett, JN Bull, H Cederquist, S Indrajith… - Nature …, 2023 - nature.com
After decades of searching, astronomers have recently identified specific Polycyclic Aromatic
Hydrocarbons (PAHs) in space. Remarkably, the observed abundance of cyanonaphthalene …

A Search for Heterocycles in GOTHAM Observations of TMC-1

TJ Barnum, MA Siebert, KLK Lee… - The Journal of …, 2022 - ACS Publications
We have conducted an extensive search for nitrogen-, oxygen-, and sulfur-bearing
heterocycles toward Taurus Molecular Cloud 1 (TMC-1) using the deep, broadband …

Aromatic cycles are widespread in cold clouds

M Agúndez, N Marcelino, B Tercero… - Astronomy & …, 2023 - aanda.org
We report the detection of large hydrocarbon cycles toward several cold dense clouds. We
observed four sources (L1495B, Lupus-1A, L483, and L1527) in the Q band (31− 50 GHz) …

The UMIST database for astrochemistry 2022

TJ Millar, C Walsh, M Van de Sande… - Astronomy & …, 2024 - aanda.org
Context. Detailed astrochemical models are a key component to interpret the observations of
interstellar and circumstellar molecules since they allow important physical properties of the …

Five-membered ring compounds from the ortho-benzyne + methyl radical reaction under interstellar conditions

J Bouwman, MN McCabe, CN Shingledecker… - Nature …, 2023 - nature.com
Reactive open-shell species, such as radicals and biradicals, are key intermediates in the
formation of (poly) cyclic hydrocarbon species in a variety of interstellar environments …

Detection of ethynylbenzene in TMC-1 and the interstellar search for 1, 2-diethynylbenzene

D Loru, C Cabezas, J Cernicharo, M Schnell… - Astronomy & …, 2023 - aanda.org
Aims. We investigate the outcome of an electrical discharge of naphthalene and search for
the resulting products in the Taurus Molecular Cloud (TMC-1). Methods. Using chirped pulse …