Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges

IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …

Visible light-induced transition metal catalysis

KPS Cheung, S Sarkar, V Gevorgyan - Chemical reviews, 2021 - ACS Publications
In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

Metallaphotoredox: the merger of photoredox and transition metal catalysis

AY Chan, IB Perry, NB Bissonnette, BF Buksh… - Chemical …, 2021 - ACS Publications
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Photoactive copper complexes: properties and applications

J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

Chiral photocatalyst structures in asymmetric photochemical synthesis

MJ Genzink, JB Kidd, WB Swords, TP Yoon - Chemical reviews, 2021 - ACS Publications
Asymmetric catalysis is a major theme of research in contemporary synthetic organic
chemistry. The discovery of general strategies for highly enantioselective photochemical …

Transition metal-catalyzed organic reactions under visible light: recent developments and future perspectives

WM Cheng, R Shang - ACS Catalysis, 2020 - ACS Publications
The development of transition metal (TM) catalysis for organic synthesis under visible light
without recourse to typical photoredox catalysts has become a rapidly growing area of …

Unveiling extreme photoreduction potentials of donor–acceptor cyanoarenes to access aryl radicals from aryl chlorides

J Xu, J Cao, X Wu, H Wang, X Yang… - Journal of the …, 2021 - ACS Publications
Since the seminal work of Zhang in 2016, donor–acceptor cyanoarene-based fluorophores,
such as 1, 2, 3, 5-tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN), have been widely …

Copper's rapid ascent in visible-light photoredox catalysis

A Hossain, A Bhattacharyya, O Reiser - Science, 2019 - science.org
BACKGROUND The recent resurgence and dramatic evolution of visible-light photoredox
catalysis has led to a paradigm shift in organic synthesis that encompasses activation of …

Ligand development for copper-catalyzed enantioconvergent radical cross-coupling of racemic alkyl halides

XY Dong, ZL Li, QS Gu, XY Liu - Journal of the American Chemical …, 2022 - ACS Publications
The enantioconvergent cross-coupling of racemic alkyl halides represents a powerful tool for
the synthesis of enantioenriched molecules. In this regard, the first-row transition metal …

Photoactive complexes with earth-abundant metals

OS Wenger - Journal of the American Chemical Society, 2018 - ACS Publications
In this invited Perspective, recent developments and possible future directions of research
on photoactive coordination compounds made from nonprecious transition metal elements …