The addition of X3Si–H or X2B–H (X= H, OR or R) across a C–C multiple bond is a well-
established method for incorporating silane or borane groups, respectively, into …

The last two decades have seen an impressive improvement of the use of iron as a
fascinating and valuable alternative transition metal in homogeneous catalysis in terms of …

Hydrosilylation reactions, the (commonly) anti-Markovnikov additions of silanes to
unsaturated bonds present in compounds such as alkenes and alkynes, offer numerous …

Combination of the readily available α-diimine ligand,((Ar N C (Me)) 2 Ar= 2, 6-iPr2–
C6H3),(iPrDI) with air-stable nickel (II) bis (carboxylates) generated a highly active catalyst …

High-spin pyridine diimine cobalt (II) bis (carboxylate) complexes have been synthesized
and exhibit high activity for the hydrosilylation of a range of commercially relevant alkenes …

We report on an additive-free Mn (I)-catalyzed dehydrogenative silylation of terminal
alkenes. The most active precatalyst is the bench-stable alkyl bisphosphine Mn (I) complex …

The dimeric β-diketiminate manganese hydride compound,[(2, 6-iPr2PhBDI) Mn (μ-H)] 2,
was prepared by treating [(2, 6-iPr2PhBDI) Mn (μ-Cl)] 2 with NaEt3BH. This compound was …

Computational Methods in Organometallic Catalysis Discover recent advances in the
mechanistic study of organometallic catalysis In Computational Methods in Organometallic …

The utility of commercially available Ni (II) salts, Ni (acac) 2 (acac= acetylacetonato)(1a) and
its derivatives bis (hexafluoroacetylacetonato) nickel (II)(1b) and bis (2, 2, 6, 6-tetramethyl-3 …

Cyclometallated iridium (III) complexes with 2-phenylpyridine [Ir (ppy) 2 (CNR) Cl](ppy=(2-
phenylpyridinato-C2, N), R= Xyl, Mes),[Ir (ppy) 2 (CNR) 2](OTf)(R= Xyl, Mes), and fac-[Ir …