An unprecedented protocol for a Rh (III)-catalyzed [3+ 2] annulation from simple and readily
available enaminones and iodonium ylides has been developed. The novel strategy allows …

A novel Rh (III)-catalyzed cascade alkenyl C–H activation/[3+ 2] annulation/pinacol
rearrangement reaction of enaminones with iodonium ylides has been developed. This …

Herein, a straightforward and efficient method to obtain 3a, 7a-dihydroxy hexahydro-4H-
indol-4-ones via Ru (III)-catalyzed alkenyl C (sp2)–H bond functionalization/[3+ 2] …

The palladium-catalyzed skeletal rearrangement of 3-arylcyclobutanones into 1-indanones
is reported. A Pd (0)/IMes catalyst allows for the cleavage of C (carbonyl)–C (sp3) and C …

Abstract Transition‐metal‐catalyzed [4+ 4] cycloaddition leading to cyclooctanoids has
centered on dimerization between 1, 3‐diene‐type substrates. Herein, we describe a [4σ+ …

Here, we describe a transition-metal-free condition that realized the intramolecular
acylfluorination of unactivated olefins. It was designed to access seven-membered-ring …

Developing efficient photosensitizers for C–P bond construction is highly important and
remains a challenge due to the urgently needed for the synthesis of modified nucleosides …

The first Ru (II)-catalyzed cascade C–H activation/annulation reactions of N-aryl-
pyrazolidinones with sulfoxonium ylides for the synthesis of cinnoline-fused pyrazolidinones …

Multiple contiguous quaternary carbon stereocenters (CQS) are highly challenging, yet
important structural motifs in organic synthesis. Here, we describe a visible light induced …

Highly enantioselective [1, 3] sigmatropic rearrangement represents a grand challenge in
asymmetric organocatalysis. Herein, we disclose a chiral phosphoramide (R)-NPA-Cy …