The recent advances in K 2 S 2 O 8-mediated cyclization/coupling reactions via an oxidative transformation

S Kumar, K Padala - Chemical Communications, 2020 - pubs.rsc.org
Transition metal-free organic transformations using K2S2O8 is one of the most efficient
methods for the formation of carbon–carbon/carbon–heteroatom bond in organic synthesis …

Direct Functionalization of para‐Quinones: A Historical Review and New Perspectives

R Kumar Jha, S Kumar - European Journal of Organic …, 2024 - Wiley Online Library
The direct functionalization of quinones has always fascinated research communities due to
their biological and redox activities and subsequent application. Quinone motifs play a vital …

Late-stage C–H alkylation of heterocycles and 1, 4-quinones via oxidative homolysis of 1, 4-dihydropyridines

Á Gutiérrez-Bonet, C Remeur, JK Matsui… - Journal of the …, 2017 - ACS Publications
Under oxidative conditions, 1, 4-dihydropyridines (DHPs) undergo a homolytic cleavage,
forming exclusively a Csp3-centered radical that can engage in the C–H alkylation of …

Metal-, photocatalyst-, and light-free, late-stage c–h alkylation of heteroarenes and 1, 4-quinones using carboxylic acids

DR Sutherland, M Veguillas, CL Oates, AL Lee - Organic letters, 2018 - ACS Publications
Contrary to the accepted convention, this work shows that Minisci-type C–H alkylation does
not require any metal, photocatalyst, light, or prefunctionalization of the readily available and …

Sodium salts (NaI/NaBr/NaCl) for the halogenation of imidazo-fused heterocycles

R Semwal, C Ravi, R Kumar, R Meena… - The Journal of Organic …, 2018 - ACS Publications
We report herein an effective method for the halogenation of imidazo-fused heterocycles
using readily available sodium salts (NaCl/NaBr/NaI) as halogen source and K2S2O8 (or) …

Stainless steel-initiated thiosulfonylations of unactivated alkenes under solvent-free conditions in a mixer mill

D Kong, C Bolm - Green Chemistry, 2022 - pubs.rsc.org
Stainless steel-initiated thiosulfonylations of unactivated alkenes under solvent-free conditions in
a mixer mill - Green Chemistry (RSC Publishing) DOI:10.1039/D2GC02519A Royal Society of …

K 2 S 2 O 8 mediated C-3 arylation of quinoxalin-2 (1 H)-ones under metal-, photocatalyst-and light-free conditions

NB Dutta, M Bhuyan, G Baishya - RSC advances, 2020 - pubs.rsc.org
Two facile and effective C-3 arylation protocols of quinoxalin-2 (1H)-ones with
arylhydrazines and aryl boronic acids respectively via free radical cross-coupling reactions …

Mn (OAc) 3* 2H2O promoted addition of arylboronic acids to quinoxalin-2-ones

B Ramesh, CR Reddy, GR Kumar, BVS Reddy - Tetrahedron Letters, 2018 - Elsevier
A simple method has been developed for the synthesis of 3-aryl quinoxalin-2-one
derivatives through an oxidative cross-coupling of arylboronic acids with quinoxalin-2-ones …

C–H arylation reactions through aniline activation catalysed by a PANI-gC 3 N 4-TiO 2 composite under visible light in aqueous medium

L Wang, J Shen, S Yang, W Liu, Q Chen, M He - Green Chemistry, 2018 - pubs.rsc.org
A PANI (polyaniline)-g-C3N4-TiO2 composite was prepared and found to be efficient for
radical C–H arylation reactions. The arylation process involved coupling of in situ generated …

Recent advances in direct functionalization of quinones

Y Wang, S Zhu, LH Zou - European Journal of Organic …, 2019 - Wiley Online Library
Developing methods for the direct functionalization of quinones for assembly of highly
functionalized quinones or bioactive natural products is an essential topic in the field of …