Comprehensive overview of polyoxometalates for electrocatalytic hydrogen evolution reaction

Z Zeb, Y Huang, L Chen, W Zhou, M Liao… - Coordination Chemistry …, 2023 - Elsevier
Electrocatalytic water splitting via hydrogen evolution reaction (HER) from renewable energy
sources is an attractive alternative to produce hydrogen, but it still encounters the limitations …

Recent advances in confining polyoxometalates and the applications

L Guo, L He, Q Zhuang, B Li, C Wang, Y Lv, J Chu… - Small, 2023 - Wiley Online Library
Polyoxometalates (POMs) are widely used in catalysis, energy storage, biomedicine, and
other research fields due to their unique acidity, photothermal, and redox features. However …

Directional shunting of photogenerated carriers in POM@ MOF for promoting nitrogen adsorption and oxidation

X Li, L Yang, Q Liu, W Bai, H Li, M Wang… - Advanced …, 2023 - Wiley Online Library
The efficient catalysis of nitrogen (N2) into high‐value N‐containing products plays a crucial
role in the N economic cycle. However, weak N2 adsorption and invalid N2 activation …

Recent advances in hybrid materials of metal nanoparticles and polyoxometalates

K Xia, K Yamaguchi, K Suzuki - … Chemie International Edition, 2023 - Wiley Online Library
Abstract Polyoxometalates (POMs), anionic metal‐oxygen nanoclusters that possess various
composition‐dependent properties, are widely used to modify the existing properties of …

A Polyoxometalate‐Based Pathologically Activated Assay for Efficient Bioorthogonal Catalytic Selective Therapy

H Zhao, C Zhao, Z Liu, J Yi, X Liu… - Angewandte Chemie …, 2023 - Wiley Online Library
Since polyoxometalates (POMs) can undergo reversible multi‐electron redox
transformations, they have been used to modulate the electronic environment of metal …

Control the Single‐, Two‐, and Three‐Photon Excited Fluorescence of Atomically Precise Metal Nanoclusters

P Pan, L Liu, L Zhang, X Wei, Y Tian… - Angewandte Chemie …, 2022 - Wiley Online Library
It remains challenging to control the single‐, two‐, and three‐photon excited fluorescence of
metal nanoclusters. In this work, the control over the non‐linear optics of metal nanoclusters …

Near-infrared photothermal conversion of polyoxometalate-modified gold nanorods for plasmon-enhanced catalysis

G Wang, X Chen, B Li, L Wu - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
Combining the high catalytic activity of polyoxometalates (POMs) and the near-infrared (NIR)
photothermal property of gold nanorods (AuNRs), POM-modified AuNR composites were …

[HTML][HTML] Ultra-stable and highly reactive colloidal gold nanoparticle catalysts protected using multi-dentate metal oxide nanoclusters

K Xia, T Yatabe, K Yonesato, S Kikkawa… - Nature …, 2024 - nature.com
Owing to their remarkable properties, gold nanoparticles are applied in diverse fields,
including catalysis, electronics, energy conversion and sensors. However, for catalytic …

High Performance Polyoxometalate-Stabilizing Pt Nanocatalysts for Quinoline Hydrogenation with Water-Mediated Dynamic Hydrogen

X Wei, Y Jiang, Y Ma, H Liao, S Dai, P An… - ACS …, 2024 - ACS Publications
In this work, a Keggin-type platinum substituted polyoxometalate (POM) is constructed by the
reaction of monolacunary phosphotungstate precursor [PW11O39] 7–with chloroplatinic …

[HTML][HTML] Polyoxometalate-based plasmonic electron sponge membrane for nanofluidic osmotic energy conversion

C Zhu, L Xu, Y Liu, J Liu, J Wang, H Sun… - Nature …, 2024 - nature.com
Nanofluidic membranes have demonstrated great potential in harvesting osmotic energy.
However, the output power densities are usually hampered by insufficient membrane …