HFIP in organic synthesis

HF Motiwala, AM Armaly, JG Cacioppo… - Chemical …, 2022 - ACS Publications
1, 1, 1, 3, 3, 3-Hexafluoroisopropanol (HFIP) is a polar, strongly hydrogen bond-donating
solvent that has found numerous uses in organic synthesis due to its ability to stabilize ionic …

Advances on the merger of electrochemistry and transition metal catalysis for organic synthesis

CA Malapit, MB Prater, JR Cabrera-Pardo, M Li… - Chemical …, 2021 - ACS Publications
Synthetic organic electrosynthesis has grown in the past few decades by achieving many
valuable transformations for synthetic chemists. Although electrocatalysis has been popular …

C–H activation

T Rogge, N Kaplaneris, N Chatani, J Kim… - Nature Reviews …, 2021 - nature.com
Transition metal-catalysed C–H activation has emerged as an increasingly powerful platform
for molecular syntheses, enabling applications to natural product syntheses, late-stage …

C–H activation: toward sustainability and applications

T Dalton, T Faber, F Glorius - ACS Central Science, 2021 - ACS Publications
Since the definition of the “12 Principles of Green Chemistry” more than 20 years ago,
chemists have become increasingly mindful of the need to conserve natural resources and …

N-Heterocyclic carbene complexes in C–H activation reactions

Q Zhao, G Meng, SP Nolan, M Szostak - Chemical reviews, 2020 - ACS Publications
In this contribution, we provide a comprehensive overview of C–H activation methods
promoted by NHC–transition metal complexes, covering the literature since 2002 (the year …

Photoredox Catalysis for Building C–C Bonds from C(sp2)–H Bonds

CS Wang, PH Dixneuf, JF Soulé - Chemical reviews, 2018 - ACS Publications
Transition metal-catalyzed C–H bond functionalizations have been the focus of intensive
research over the last decades for the formation of C–C bonds from unfunctionalized arenes …

Photoredox catalysis in organic chemistry

MH Shaw, J Twilton… - The Journal of organic …, 2016 - ACS Publications
In recent years, photoredox catalysis has come to the forefront in organic chemistry as a
powerful strategy for the activation of small molecules. In a general sense, these approaches …

Improving photosynthesis and crop productivity by accelerating recovery from photoprotection

J Kromdijk, K Głowacka, L Leonelli, ST Gabilly, M Iwai… - Science, 2016 - science.org
Crop leaves in full sunlight dissipate damaging excess absorbed light energy as heat. When
sunlit leaves are shaded by clouds or other leaves, this protective dissipation continues for …

[HTML][HTML] Installing the “magic methyl”–C–H methylation in synthesis

D Aynetdinova, MC Callens, HB Hicks… - Chemical Society …, 2021 - pubs.rsc.org
The selective and efficient C–H methylation of sp2 and sp3 carbon centres has become a
powerful transformation in the synthetic toolbox. Due to the potential for profound changes to …

[HTML][HTML] Mild metal-catalyzed C–H activation: examples and concepts

T Gensch, MN Hopkinson, F Glorius… - Chemical Society …, 2016 - pubs.rsc.org
Organic reactions that involve the direct functionalization of non-activated C–H bonds
represent an attractive class of transformations which maximize atom-and step-economy …