Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient
synthesis of useful optically active compounds. They are largely categorized into two …

Hypervalent aryliodoumiums are intensively investigated as arylating agents. They are
excellent surrogates to aryl halides, and moreover they exhibit better reactivity, which allows …

The efficacy and synthetic versatility of asymmetric organocatalysis have contributed
enormously to the field of organic synthesis since the early 2000s. As asymmetric …

The hallmark of nucleophilic phosphine catalysis is the initial nucleophilic addition of a
phosphine to an electrophilic starting material, producing a reactive zwitterionic …

Asymmetric phosphine catalysis showcasing remarkable progress over the past two
decades has emerged as a key synthetic platform for the creation of molecular frameworks …

Conspectus Axially chiral compounds have received much attention from chemists because
of their widespread appearance in natural products, biologically active compounds, and …

Conspectus Atropisomeric compounds are found extensively as natural products, as ligands
for asymmetric transition-metal catalysis, and increasingly as bioactive and pharmaceutically …

Nucleophilic phosphine catalysis is a practical and powerful tool for the synthesis of various
heterocyclic compounds with the advantages of environmentally friendly, metal-free, and …

In recent years, the catalytic enantioselective reactions of p‐QMs have drawn much
attention, because of their distinctive reactivities. As such, a variety of chiral catalytic systems …

Abstract Axially chiral 1, 1′-binaphthols (BINOLs) and 1, 1′-spirobiindanes (SPINOLs)
have achieved great success in the field of asymmetric catalysis. Although several …