BS Komarova, NS Novikova, AG Gerbst… - The Journal of …, 2023 - ACS Publications
Stereospecific α-glucosylation of primary and secondary OH-group at carbohydrate acceptors is achieved using glucosyl N-phenyl-trifluoroacetimidate (PTFAI) donor protected …
HH Trinderup, L Juul-Madsen, L Press… - The Journal of …, 2022 - ACS Publications
A systematic study of the effect of various 6-O-acyl groups on anomeric selectivity in glucosylations with thioglycoside donors was conducted. All eight different esters were …
P Gallego-Lobillo, EG Doyagüez… - Journal of Agricultural …, 2021 - ACS Publications
Trehalose, α-d-glucopyranosyl-(1↔ 1)-α-d-glucopyranoside, is a disaccharide with multiple effects on the human body. Synthesis of new trehalose derivatives was investigated through …
BS Komarova, VS Dorokhova, YE Tsvetkov… - Organic Chemistry …, 2018 - pubs.rsc.org
Two glucosyl donors, which allowed for the α-selective glucosylation of primary hydroxyl groups, were designed using a combination of acyl groups capable of remote participation …
Herein, we report, for the first time, a strategy to differentiate O4/O4′ positions of 1, 1′-α, α- trehalose via regioselective protection or site-selective functionalization and its application …
H Zhang, C Zeng, Q Zhu, D Zhu… - Chemistry–A European …, 2024 - Wiley Online Library
Chemical synthesis of an orthogonally protected hexasaccharide relevant to the reducing‐ end half of axinelloside A, a highly sulfated marine lipopolysaccharide, is disclosed. The …
SS Nalpe, S Jana, SS Kulkarni - Organic Letters, 2023 - ACS Publications
A short and efficient methodology has been developed to synthesize an analogue of a lipooligosaccharide from Mycobacterium linda isolated from Crohn's disease. The total …
CM Carthy, M Tacke, X Zhu - European Journal of Organic …, 2019 - Wiley Online Library
For the first time, N‐trifluoromethylthiosaccharin was used to activate thioglycosides in the presence of catalytic amounts of TMSOTf. The results show that the activated thioglycosides …
2, 3‐Dideoxy‐3C‐formyl β‐C‐aryl/alkyl furanosides were synthesized in a stereoselective manner through a cascade of Prins reaction and pinacol‐type rearrangement of an …