Sulfilimines are versatile synthetic intermediates and important moieties in bioactive
molecules. However, their applications in drug discovery are underexplored, and efficient …

A mechanochemical copper-catalyzed oxidative amination of primary sulfinamides has been
developed, leading to N H-sulfonimidamides in moderate to good yields under solvent-free …

Herein we report the first transition metal‐catalyzed approach to the enantioenriched
synthesis of cyclic sulfonimidamides relying on commercially available palladium catalysts …

Sulfur‐centered electrophilic'warheads' have emerged as key components for chemical
proteomic probes through sulfur‐exchange chemistry (SuFEx) with protein nucleophiles …

Advancements in synthetic organic chemistry are closely related to understanding substrate
and catalyst reactivities through detailed mechanistic studies. Traditional mechanistic …

Significance: Sigman, Miller, Lim, and co-workers report an enantioselective acylation of
sulfonimidamides catalyzed by a cinchona alkaloid derivative. High-throughput …