The question of ligand noninnocence in Cu corroles has long been a topic of discussion.
Presented herein is a Cu K-edge X-ray absorption spectroscopy (XAS) study, which …

Vilsmeier–Haack formylation of ReO and Au meso-triarylcorroles over 16–18 hours affords
moderate to good yields (47–65%) of the ReO-3-formyl and Au-3, 17-diformyl derivatives in …

Presented herein is a detailed multitechnique investigation of ligand noninnocence in S= 3/2
manganese corrole derivatives at the formal MnIV oxidation state. The Soret maxima of Mn …

Broadly, the industrial applications of hydrazine cause environmental pollution and damage
to living organisms because of the high toxicity of hydrazine. Therefore, monitoring …

Alkylation of one of the inner‐core nitrogen atoms is one possible approach to obtain
dianionic corrole ligands, suitable for the coordination of divalent metal ions, such as PdII …

Acid-catalyzed condensation of pyrrole, 4-trifluoromethylbenzaldehyde, and azulene,
followed by DDQ oxidation, has resulted in the isolation of the novel macrocycle …

Given that noninnocent and metalloradical-type electronic structures are ubiquitous among
dipyrrin-bisphenolate (DPP) complexes, we synthesized the gold (III) derivatives as …

Single-crystal X-ray structures were obtained for the copper and μ-oxodiiron complexes of 2,
3, 7, 8, 12, 13, 17, 18-octafluoro-5, 10, 15-triphenylcorrole, hereafter denoted as Cu [F8TPC] …

UV–vis spectrophotometric titrations have been carried out on meso-tris (o/m/p-
aminophenyl) corrole (H3 [o/m/p-TAPC]) and meso-triphenylcorrole (H3 [TPC]) in dimethyl …

Although rather delicate on account of their propensity to undergo deiodination, β-
octaiodoporphyrinoids are of considerable interest as potential precursors to novel β …