Probing the binding and activation of small molecules by gas-phase transition metal clusters via IR spectroscopy

A Fielicke - Chemical Society Reviews, 2023 - pubs.rsc.org
Isolated transition metal clusters have been established as useful models for extended metal
surfaces or deposited metal particles, to improve the understanding of their surface …

Chemistry with methane: concepts rather than recipes

H Schwarz - Angewandte Chemie International Edition, 2011 - Wiley Online Library
Four seemingly simple transformations related to the chemistry of methane will be
addressed from mechanistic and conceptual points of view: 1) metal‐mediated …

Gas‐phase catalysis by atomic and cluster metal ions: the ultimate single‐site catalysts

DK Böhme, H Schwarz - Angewandte Chemie International …, 2005 - Wiley Online Library
Gas‐phase experiments with state‐of‐the‐art techniques of mass spectrometry provide
detailed insights into numerous elementary processes. The focus of this Review is on …

Selective activation of alkanes by gas-phase metal ions

J Roithova, D Schroder - Chemical reviews, 2010 - ACS Publications
The importance of the selective activation of alkanes for science and technology in the
forthcoming decades does not need to be explicitly pointed out in this thematic issue of …

Clusters: Structure, energetics, and dynamics of intermediate states of matter

AW Castleman, KH Bowen - The Journal of Physical Chemistry, 1996 - ACS Publications
The field of cluster research can trace its origins back to the mid-nineteenth century when
early studies of colloids, aerosols, and nucleation phenomena were reported. The field …

Size dependent catalysis with CTAB-stabilized gold nanoparticles

R Fenger, E Fertitta, H Kirmse… - Physical Chemistry …, 2012 - pubs.rsc.org
CTAB-stabilized gold nanoparticles were synthesized by applying the seeding-growth
approach in order to gain information about the size dependence of the catalytic reduction of …

C H and C C Bond Activation by Bare Transition‐Metal Oxide Cations in the Gas Phase

D Schröder, H Schwarz - Angewandte Chemie International …, 1995 - Wiley Online Library
Over the last decade the gas‐phase chemistry of bare transition‐metal oxide cations MO+
has received considerable attention. This interest is primarily due to the particular role of …

Synthetic chemistry with nitrous oxide

K Severin - Chemical Society Reviews, 2015 - pubs.rsc.org
This review article summarizes efforts to use nitrous oxide (N2O,'laughing gas') as a reagent
in synthetic chemistry. The focus will be on reactions which are carried out in homogeneous …

Activation of hydrogen and methane by thermalized FeO+ in the gas phase as studied by multiple mass spectrometric techniques

D Schröder, H Schwarz, DE Clemmer, Y Chen… - International journal of …, 1997 - Elsevier
The ion-molecule reactions of thermalized iron-oxide cation FeO+ with dihydrogen and
methane have been studied by three different experimental techniques: Fourier transform …

Ionic clusters

AW Castleman Jr, RG Keesee - Chemical Reviews, 1986 - ACS Publications
Studies devoted to elucidating the mechanisms of formation and the properties of small
clusters consisting of molecules attached to ions have dramatically in-creased during the …