Diazine-based thermally activated delayed fluorescence chromophores

S Achelle, M Hodée, J Massue, A Fihey, C Katan - Dyes and Pigments, 2022 - Elsevier
Diazines are electron deficient six-membered aromatic rings heterocycles which have
successfully been employed in the design of a wide range of push-pull chromophores for …

Correlating exciton dynamics of thermally activated delayed-fluorescence emitters to efficiency roll-off in OLEDs

M Hasan, A Shukla, M Mamada, C Adachi, SC Lo… - Physical Review …, 2022 - APS
Physical parameters, such as decay rates and photoluminescence (PL) quantum
efficiencies, associated with thermally activated delayed fluorescence (TADF) emitters play a …

Tuning of HOMO-LUMO localization for achieving thermally activated delayed fluorescence

R Skaisgiris, T Serevičius, J Dodonova… - Journal of …, 2022 - Elsevier
High emission yield and rapid reverse intersystem crossing are essential for efficient
thermally activated delayed fluorescence (TADF) compounds. In this paper, we show that …

Triphenylamino or 9-phenyl carbazolyl-substituted pyrimidine-5-carbonitriles as bipolar emitters and hosts with triplet harvesting abilities

U Tsiko, D Volyniuk, V Andruleviciene… - Materials Today …, 2022 - Elsevier
To obtain highly efficient organic semiconductors exhibiting fast emission decays, triplet-
harvesting abilities and good bipolar charge-transporting properties for optoelectronic …

Tuning the emission and exciton utilization mechanisms of pyrazine-based multi-carbazole emitters and their use in organic light-emitting diodes

D Chen, L Zhang, T Matulaitis, DB Cordes… - Journal of Materials …, 2023 - pubs.rsc.org
Thermally activated delayed fluorescence (TADF) and hot excitons are two distinct exciton
harvesting mechanisms that can lead to 100% internal quantum efficiency in organic light …

1, 4-Bis (trifluoromethyl) benzene as a new acceptor for the design and synthesis of emitters exhibiting efficient thermally activated delayed fluorescence and …

L Skhirtladze, K Lietonas, A Bucinskas… - Journal of Materials …, 2022 - pubs.rsc.org
1, 4-Bis (trifluoromethyl) benzene as a new acceptor with hydrogen bonding sites together
with phenoxazine, phenothiazine or 9, 9-dimethyl-9-10-dihydroacridine as donor moieties …

Single-exponential solid-state delayed fluorescence decay in TADF compounds with minimized conformational disorder

T Serevičius, R Skaisgiris, I Fiodorova… - Journal of Materials …, 2021 - pubs.rsc.org
Thermally activated delayed fluorescence (TADF) compounds with rapid triplet
upconversion in solutions frequently yield drastically lowered upconversion rates in solid …

Temporal Dynamics of Solid-State Thermally Activated Delayed Fluorescence: Disorder or Ultraslow Solvation?

T Serevičius, R Skaisgiris, J Dodonova… - The Journal of …, 2022 - ACS Publications
Time-resolved emission spectra of thermally activated delayed fluorescence (TADF)
compounds in solid hosts demonstrate significant temporal shifts. To explain the shifts, two …

Styrylpyrimidine chromophores with bulky electron-donating substituents: experimental and theoretical investigation

M Hodée, J Massue, S Achelle, A Fihey… - Physical Chemistry …, 2023 - pubs.rsc.org
Styrylpyrimidines with bulky 9, 9-dimethylacridan, phenoxazine and phenothiazine electron-
donating fragments were designed. Thermally activated delayed fluorescence (TADF) …

Pyrimidine-based thermally activated delayed fluorescent materials with unique asymmetry for highly-efficient organic light-emitting diodes

B Li, Z Li, X Song, F Guo, Y Wang, S Gao, Y Zhang - Dyes and Pigments, 2022 - Elsevier
We have designed and synthesized three thermally activated delayed fluorescent (TADF)
emitters as 2-phenypyrimidine (PPM)-10H-spiro [acridan-9, 9′-fluorene](SPAc) hybrids …