Polymer nanocomposite dielectrics: understanding the matrix/particle interface

S Wang, Z Luo, J Liang, J Hu, N Jiang, J He, Q Li - ACS nano, 2022 - ACS Publications
Polymer nanocomposite dielectrics possess exceptional electric properties that are absent
in the pristine dielectric polymers. The matrix/particle interface in polymer nanocomposite …

Dynamics of polymer segments, polymer chains, and nanoparticles in polymer nanocomposite melts: A review

EJ Bailey, KI Winey - Progress in Polymer Science, 2020 - Elsevier
The addition of nanoparticles (NPs) to a polymer matrix, forming a polymer nanocomposite
(PNC), is known to alter the microscopic dynamic processes of both species which leads to …

Review on the processing and properties of polymer nanocomposites and nanocoatings and their applications in the packaging, automotive and solar energy fields

K Müller, E Bugnicourt, M Latorre, M Jorda… - Nanomaterials, 2017 - mdpi.com
For the last decades, nanocomposites materials have been widely studied in the scientific
literature as they provide substantial properties enhancements, even at low nanoparticles …

Interphase in polymer nanocomposites

J Huang, J Zhou, M Liu - JACS Au, 2022 - ACS Publications
The lightweight and high-strength functional nanocomposites are important in many
practical applications. Natural biomaterials with excellent mechanical properties provide …

Glass transition of polymers in bulk, confined geometries, and near interfaces

S Napolitano, E Glynos, NB Tito - Reports on Progress in Physics, 2017 - iopscience.iop.org
When cooled or pressurized, polymer melts exhibit a tremendous reduction in molecular
mobility. If the process is performed at a constant rate, the structural relaxation time of the …

Dynamics at the polymer/nanoparticle interface in poly (2-vinylpyridine)/silica nanocomposites

AP Holt, PJ Griffin, V Bocharova, AL Agapov… - …, 2014 - ACS Publications
The static and dynamic properties of poly (2-vinylpyridine)/silica nanocomposites are
investigated by temperature modulated differential scanning calorimetry, broadband …

Silica–epoxy vitrimer nanocomposites

A Legrand, C Soulié-Ziakovic - Macromolecules, 2016 - ACS Publications
Reinforced silica–epoxy vitrimer nanocomposites have been made in a solvent-free, easily
processable, and economical way with filler contents up to 40 wt%. Increasing silica content …

Network dynamics in nanofilled polymers

GP Baeza, C Dessi, S Costanzo, D Zhao… - Nature …, 2016 - nature.com
It is well accepted that adding nanoparticles (NPs) to polymer melts can result in significant
property improvements. Here we focus on the causes of mechanical reinforcement and …

Revealed architectures of adsorbed polymer chains at solid-polymer melt interfaces

P Gin, N Jiang, C Liang, T Taniguchi, B Akgun… - Physical review …, 2012 - APS
We report the chain conformations of polymer molecules accommodated at the solid-
polymer melt interfaces in equilibrium. Polystyrene “Guiselin” brushes (adsorbed layers) with …

Controlling Interfacial Dynamics: Covalent Bonding versus Physical Adsorption in Polymer Nanocomposites

AP Holt, V Bocharova, S Cheng, AM Kisliuk, BT White… - ACS …, 2016 - ACS Publications
It is generally believed that the strength of the polymer–nanoparticle interaction controls the
modification of near-interface segmental mobility in polymer nanocomposites (PNCs) …