Hydrothermal transport, deposition, and fractionation of the REE: Experimental data and thermodynamic calculations

A Migdisov, AE Williams-Jones, J Brugger… - Chemical …, 2016 - Elsevier
For many years, our understanding of the behavior of the REE in hydrothermal systems was
based on semi-empirical estimates involving extrapolation of thermodynamic data obtained …

A review of the coordination chemistry of hydrothermal systems, or do coordination changes make ore deposits?

J Brugger, W Liu, B Etschmann, Y Mei, DM Sherman… - Chemical …, 2016 - Elsevier
The hydration and complexation of metals in hydrothermal fluids are key processes
controlling the mobility of elements in the Earth's crust, leading to the formation of ore …

Hydrated metal ions in aqueous solution: How regular are their structures?

I Persson - Pure and Applied Chemistry, 2010 - degruyter.com
The hydration reaction is defined as the transfer of an ion or neutral chemical species from
the gaseous phase into water, M n+(g)→ M n+(aq). In this process, water molecules bind to …

Adsorption of REEs on kaolinite and halloysite: A link to the REE distribution on clays in the weathering crust of granite

M Yang, X Liang, L Ma, J Huang, H He, J Zhu - Chemical Geology, 2019 - Elsevier
The clay minerals, kaolinite and halloysite are dominant hosts for rare earth elements
(REEs) in the weathered crust elution-deposited REE deposits. However, the accumulation …

Alternatives to gadolinium-based metal chelates for magnetic resonance imaging

S Viswanathan, Z Kovacs, KN Green… - Chemical …, 2010 - ACS Publications
Magnetic resonance imaging (MRI) has been immensely valuable in diagnostic clinical
imaging over the last few decades owing to its exceptional spatial and anatomical …

Revised ionic radii of lanthanoid (III) ions in aqueous solution

P D'Angelo, A Zitolo, V Migliorati, G Chillemi… - Inorganic …, 2011 - ACS Publications
A new set of ionic radii in aqueous solution has been derived for lanthanoid (III) cations
starting from a very accurate experimental determination of the ion–water distances …

[HTML][HTML] The chemical consequences of the gradual decrease of the ionic radius along the Ln-series

JA Peters, K Djanashvili, CFGC Geraldes… - Coordination Chemistry …, 2020 - Elsevier
In the periodical system, the lanthanides (the 15 elements in the periodic table between
barium and hafnium) are unique in the sense that their trivalent cations have their valence …

Precipitation of rare earth elements from acid mine drainage by CO2 mineralization process

BV Hassas, M Rezaee, SV Pisupati - Chemical Engineering Journal, 2020 - Elsevier
Abstract Acid Mine Drainage (AMD) has been of environmental concern for decades but
found to be a viable source of critical Elements (CEs), including Rare Earth Elements …

Selective precipitation of rare earth and critical elements from acid mine drainage-Part I: Kinetics and thermodynamics of staged precipitation process

BV Hassas, Y Shekarian, M Rezaee - Resources, Conservation and …, 2023 - Elsevier
Critical elements (CEs) have been in the spotlight recently due to their promising role in
green energy transition and high-tech developments. Secondary resources, such as acid …

Coordination chemistry of lanthanide ions with X-(CH2-COO-) 2 (X= O, NH, S) ligands: The leading role of X as carboxylate-connecting group

J Torres, C Kremer - Coordination Chemistry Reviews, 2023 - Elsevier
Oxydiacetate, iminodiacetate, and thiodiacetate are flexible dicarboxilates which have been
used as chelating agents towards d-metal ions for decades. They differ among each other …