[HTML][HTML] A critical review of magnesium silicate hydrate (MSH) phases for binder applications

H Sreenivasan, E Bernard, HS Santos… - Cement and Concrete …, 2024 - Elsevier
Hydrated magnesium silicate materials are promising binding materials for applications as
alternative cementitious materials and may offer a lower carbon footprint than conventional …

Mont Terri rock laboratory, 20 years of research: introduction, site characteristics and overview of experiments

P Bossart, F Bernier, J Birkholzer, C Bruggeman… - Mont Terri Rock …, 2018 - Springer
Geologic repositories for radioactive waste are designed as multi-barrier disposal systems
that perform a number of functions including the long-term isolation and containment of …

Cemdata18: A chemical thermodynamic database for hydrated Portland cements and alkali-activated materials

B Lothenbach, DA Kulik, T Matschei, M Balonis… - Cement and Concrete …, 2019 - Elsevier
Thermodynamic modelling can reliably predict hydrated cement phase assemblages and
chemical compositions, including their interactions with prevailing service environments …

[HTML][HTML] Stability of hydrotalcite (Mg-Al layered double hydroxide) in presence of different anions

E Bernard, WJ Zucha, B Lothenbach… - Cement and Concrete …, 2022 - Elsevier
MgO contained in cementitious materials is experimentally observed to precipitate as poorly
crystalline hydrotalcite (Mg-Al LDH). However, the geochemical modelling of hydrotalcite is …

[HTML][HTML] Phase changes in cementitious materials exposed to saline solutions

K De Weerdt, E Bernard, W Kunther… - Cement and Concrete …, 2023 - Elsevier
This article summarizes long-term degradation mechanisms of cementitious materials in
contact with fresh and saline solutions based on a review of experimental observations in …

Characterization of magnesium silicate hydrate (MSH)

E Bernard, B Lothenbach, C Chlique… - Cement and concrete …, 2019 - Elsevier
In this study, the structure of synthetic magnesium silicate hydrated phases (MSH) and the
distribution of water as a function of the Mg/Si ratio were investigated. Different analytical …

Effect of magnesium on calcium silicate hydrate (CSH)

E Bernard, B Lothenbach, F Le Goff, I Pochard… - Cement and Concrete …, 2017 - Elsevier
The addition of MgCl 2 to synthetic calcium silicate hydrate (CSH) with Ca/Si= 0.8 lowers the
pH values below 10. Experimental observations and thermodynamic calculations show the …

Magnesium and calcium silicate hydrates, Part I: Investigation of the possible magnesium incorporation in calcium silicate hydrate (CSH) and of the calcium in …

E Bernard, B Lothenbach, C Cau-Dit-Coumes… - Applied …, 2018 - Elsevier
Calcium silicate hydrate (CSH) and magnesium silicate hydrate (MSH) have been described
as two separate phases. This work investigates their stability domains and the possible …

Aluminum incorporation into magnesium silicate hydrate (MSH)

E Bernard, B Lothenbach, C Cau-Dit-Coumes… - Cement and concrete …, 2020 - Elsevier
The incorporation of aluminum in magnesium silicate hydrate (MSH) phases was
investigated. Magnesium (alumino) silicate hydrate (M-(A-) SH) with Mg/Si ratios equal to 1.1 …

Magnesium and calcium silicate hydrates, Part II: Mg-exchange at the interface “low-pH” cement and magnesium environment studied in a CSH and MSH model …

E Bernard, A Dauzères, B Lothenbach - Applied Geochemistry, 2018 - Elsevier
Abstract “Low-pH” cementitious materials have been developed in the context of nuclear
wastes encapsulation to reduce the alkaline plume and the early hydration heat causing …