Click chemistry strategies for the accelerated synthesis of functional macromolecules

Z Geng, JJ Shin, Y Xi, CJ Hawker - Journal of Polymer Science, 2021 - Wiley Online Library
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …

Sulfur chemistry in polymer and materials science

H Mutlu, EB Ceper, X Li, J Yang… - Macromolecular …, 2019 - Wiley Online Library
Sulfur and its functional groups are major players in an area of exciting research taking
place in modern polymer and materials science, both in academia and industry. In fact …

Pyridyl disulfide-based thiol–disulfide exchange reaction: Shaping the design of redox-responsive polymeric materials

I Altinbasak, M Arslan, R Sanyal, A Sanyal - Polymer Chemistry, 2020 - pubs.rsc.org
Recent years have witnessed an increase in the utilization of stimuli-responsive polymers in
various areas of materials and biological sciences. In particular, disulfide linkage containing …

Thioester functional polymers

S Aksakal, R Aksakal, CR Becer - Sulfur‐Containing Polymers …, 2021 - Wiley Online Library
Inspired by the abundance and versatility of thioester in nature, much attention has been
paid to thioester functionalized materials, allowing applications that range from responsive …

Nucleophilic Thiol-yne reaction in Macromolecular Engineering: From synthesis to applications

O Daglar, S Luleburgaz, E Baysak, US Gunay… - European Polymer …, 2020 - Elsevier
The developments in synthetic polymer chemistry have devoted to meet the huge demand
required to create efficient, high yield, and operationally simple chemical methods that can …

Direct-ink-write cross-linkable bottlebrush block copolymers for on-the-fly control of structural color

S Jeon, YL Kamble, H Kang, J Shi… - Proceedings of the …, 2024 - National Acad Sciences
Additive manufacturing capable of controlling and dynamically modulating structures down
to the nanoscopic scale remains challenging. By marrying additive manufacturing with self …

Fully Degradable Thioester-Functional Homo-and Alternating Copolymers Prepared through Thiocarbonyl Addition–Ring-Opening RAFT Radical Polymerization

MP Spick, NM Bingham, Y Li, J De Jesus… - …, 2020 - ACS Publications
The radical ring-opening polymerization (RROP) of thionolactones provides access to
thioester backbone-functional copolymers but has, to date, only been demonstrated on …

Thiol-triggered deconstruction of bifunctional silyl ether terpolymers via an SN Ar-triggered cascade

CM Brown, KEL Husted, Y Wang, LJ Kilgallon… - Chemical …, 2023 - pubs.rsc.org
While Si-containing polymers can often be deconstructed using chemical triggers such as
fluoride, acids, and bases, they are resistant to cleavage by mild reagents such as biological …

Click and multicomponent reactions work together for polymer chemistry

U Tunca - Macromolecular Chemistry and Physics, 2018 - Wiley Online Library
This article investigates the current combinations of click and multicomponent reactions
(MCRs) to produce complex macromolecular structures through polymer–polymer …

Non‐activated Esters as Reactive Handles in Direct Post‐Polymerization Modification

JFR Van Guyse, Y Bernhard, A Podevyn… - Angewandte …, 2023 - Wiley Online Library
Non‐activated esters are prominently featured functional groups in polymer science, as
ester functional monomers display great structural diversity and excellent compatibility with a …