Polymer networks built out of dynamic covalent bonds offer the potential to translate the
control and tunability of chemical reactions to macroscopic physical properties. Under …

Covalent adaptable networks (CANs) are covalently cross-linked polymers that may be
reshaped via cross-linking and/or strand exchange at elevated temperatures. They …

Thermoset elastomers are widely used in industry and frontier research due to their
advantage of mechanical robustness, high thermal/chemical resistance, and good …

Vitrimers constitute a fascinating class of polymer materials that make the link between the
historically opposed 3D networks (thermosets) and linear polymers (thermoplastics). Their …

We report a straightforward chemical strategy to tackle current challenges of irreversible
deformation in low Tg vitrimers at operating temperature. In particular, vinylogous urethane …

Vitrimers are polymer networks in which associative exchange reactions can take place
under specific conditions, thus conferring reprocessability to insoluble materials. Recently …

In this study, β-amino esters, prepared by the aza-Michael addition of an amine to an
acrylate moiety, are investigated as building blocks for the formation of dynamic covalent …

Mechanically durable polymer network electrolytes are desirable for batteries; however,
covalent cross-linking adversely affects their large-scale manufacturing, and they are difficult …

Dynamic networks couple the robust nature of thermosets with the shapeability and
recyclability of thermoplastics. Though a wealth of exchange chemistries can be leveraged …

Thermosets and thermoset composites constitute an extraordinary challenge for recycling
and participation in a circular economy because their permanent covalent cross-links …