Due to their atomically precise structures and intriguing chemical/physical properties, metal
nanoclusters are an emerging class of modular nanomaterials. Photo-luminescence (PL) is …

Among the d10 coinage metal complexes, cyclic trinuclear complexes (CTCs) or trinuclear
metallocycles with intratrimer metal–metal interactions are fascinating and important metal …

The dissociation process of glutathione− gold (I) polymers in aqueous solution resulted in
the formation of a class of∼ 2 nm gold nanoparticles. Different from the same sized but …

A trinuclear Au (I) pyrazolate complex bearing long alkyl chains (1) in hexane self-
assembles via a Au (I)− Au (I) metallophilic interaction, to form a red-luminescent organogel …

Synthetic details, solid-state structures, and photophysical properties of a group of trimeric
copper (I) complexes containing pyrazolate ligands are described. The reaction of copper (I) …

Varying the coinage metal in cyclic trinuclear pyrazolate complexes is found to significantly
affect the solid-state packing, photophysics, and acid− base properties. The three isoleptic …

A photophysical study is reported for the trinuclear copper (I) complex {[3, 5-(CF3) 2Pz] Cu}
3. The neutral compound exhibits multicolor bright phosphorescent emissions both in the …

In 1990, Fujita and co-workers described the first example of a rationally designed
metallacycle, the molecular square [{Pd (en)(μ-4, 4′-bipy)} 4](NO3) 8, prepared by self …

The last two decades have seen a renaissance in interest in the chemistry of the main group
elements. In particular research on the metals of group 13 (aluminium, gallium, indium and …

The design and self-assembly of three supramolecular triangles is described. A novel 60°
corner unit directs the exclusive formation of triangular assemblies that are not in detectable …