Bio-based 1, 4-butanediol and tetrahydrofuran synthesis: perspective
Y Zhu, J Yang, F Mei, X Li, C Zhao - Green Chemistry, 2022 - pubs.rsc.org
1, 4-Butanediol (1, 4-BDO) and tetrahydrofuran (THF) are important feedstocks for the
synthesis of polyurethane elastomers, polybutylene succinate (PBS), polybutylene …
synthesis of polyurethane elastomers, polybutylene succinate (PBS), polybutylene …
Perspective on catalyst development for glycerol reduction to C3 chemicals with molecular hydrogen
Y Nakagawa, M Tamura, K Tomishige - Research on Chemical …, 2018 - Springer
Recent developments in catalytic reduction with H 2 of glycerol, which is a by-product of
biodiesel manufacture, and the involved chemistry are summarized and reviewed. There are …
biodiesel manufacture, and the involved chemistry are summarized and reviewed. There are …
Transition metal-catalyzed deoxydehydration: missing pieces of the puzzle
FC Jentoft - Catalysis Science & Technology, 2022 - pubs.rsc.org
Deoxydehydration (DODH) is a transformation that converts a vicinal diol into an olefin with
the help of a sacrificial reductant. The reaction has drawn interest in the past 25 years for its …
the help of a sacrificial reductant. The reaction has drawn interest in the past 25 years for its …
The deoxydehydration (DODH) reaction: a versatile technology for accessing olefins from bio-based polyols
NN Tshibalonza, JCM Monbaliu - Green Chemistry, 2020 - pubs.rsc.org
This review provides a complete overview of the deoxydehydration (DODH) reaction
including metal-free and transition metal-based DODH processes for the upgrading of bio …
including metal-free and transition metal-based DODH processes for the upgrading of bio …
Utilization of Ni as a non-noble-metal co-catalyst for ceria-supported rhenium oxide in combination of deoxydehydration and hydrogenation of vicinal diols
K Yamaguchi, Y Nakagawa, C Li, M Yabushita… - ACS …, 2022 - ACS Publications
Removal of vicinal diols by combination of deoxydehydration and hydrogenation (DODH+
HG) was carried out over the mixture of ReO x/CeO2 and CeO2-supported base metals with …
HG) was carried out over the mixture of ReO x/CeO2 and CeO2-supported base metals with …
Kinetic Modeling of Erythritol Deoxydehydration and Consecutive Hydrogenation over the ReOx-Pd/CeO2 Catalyst
The reaction kinetics of deoxydehydration+ hydrogenation (DODH+ HG; didehydroxylation)
of erythritol to butanediols and n-butane over the ReO x-Pd/CeO2 catalyst was investigated …
of erythritol to butanediols and n-butane over the ReO x-Pd/CeO2 catalyst was investigated …
Titania-supported molybdenum oxide combined with Au nanoparticles as a hydrogen-driven deoxydehydration catalyst of diol compounds
A heterogenous catalyst for the deoxydehydration (DODH) reaction was developed using
less expensive Mo than Re as the active center. The combination of Mo with anatase-rich …
less expensive Mo than Re as the active center. The combination of Mo with anatase-rich …
Influence and stability of the surface density of MoO x on TiO 2 in deoxydehydration: structure–activity correlations
Titania supported MoOx catalysts containing varying surface densities of Mo were prepared
and well-characterized to identify the most effective MoOx species for the deoxydehydration …
and well-characterized to identify the most effective MoOx species for the deoxydehydration …
Preparation of Highly Active Monometallic Rhenium Catalysts for Selective Synthesis of 1, 4‐Butanediol from 1, 4‐Anhydroerythritol
T Wang, M Tamura, Y Nakagawa… - …, 2019 - Wiley Online Library
Butanediol can be produced from 1, 4‐anhydroerythritol through the co‐catalysis of
monometallic mixed catalysts (ReOx/CeO2+ ReOx/C) in the one‐pot reduction with H2. The …
monometallic mixed catalysts (ReOx/CeO2+ ReOx/C) in the one‐pot reduction with H2. The …
One-pot catalytic selective synthesis of 1, 4-butanediol from 1, 4-anhydroerythritol and hydrogen
A physical mixture of ReOx–Au/CeO2 and carbon-supported rhenium catalysts effectively
converted 1, 4-anhydroerythritol to 1, 4-butanediol with H2 as a reductant. The combination …
converted 1, 4-anhydroerythritol to 1, 4-butanediol with H2 as a reductant. The combination …