Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials

H Chen, WB Wei, H Lin, XT Wu - Coordination Chemistry Reviews, 2021 - Elsevier
The developments of new infrared nonlinear optical (IR-NLO) crystals with excellent
comprehensive performance are urgently needed owing to the current commercially …

Rational design of infrared nonlinear optical chalcogenides by chemical substitution

H Lin, WB Wei, H Chen, XT Wu, QL Zhu - Coordination Chemistry Reviews, 2020 - Elsevier
Infrared nonlinear optical (IR–NLO) materials are crucial for obtaining the solid-state lasers
in the spectral range of 2–20 μm, which have a broad range of applications, such as signal …

Ga-based IR nonlinear optical materials: Synthesis, structures, and properties

JX Zhang, P Feng, MY Ran, XT Wu, H Lin… - Coordination Chemistry …, 2024 - Elsevier
Infrared nonlinear optical (IR-NLO) crystals play a crucial role in the field of all-solid state
lasers. They enable the generation of tunable coherent radiations through frequency …

A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7

SP Guo, GC Guo, MS Wang, JP Zou, G Xu… - Inorganic …, 2009 - ACS Publications
Four new quaternary isostructural rare-earth thiosilicates, ZnY6Si2S14 (1), Al0. 50Dy3 (Si0.
50Al0. 50) S7 (2), Al0. 38Dy3 (Si0. 85Al0. 15) S7 (3), and Al0. 33Sm3SiS7 (4), crystallized in …

Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

P Feng, JX Zhang, MY Ran, XT Wu, H Lin, QL Zhu - Chemical Science, 2024 - pubs.rsc.org
With the continuous development of laser technology and the increasing demand for lasers
of different frequencies in the infrared (IR) spectrum, research on infrared nonlinear optical …

Strongest Second Harmonic Generation in the Polar R3MTQ7 Family: Atomic Distribution Induced Nonlinear Optical Cooperation

YF Shi, Y Chen, MC Chen, LM Wu, H Lin… - Chemistry of …, 2015 - ACS Publications
The well-known polar R3MTQ7 is a large family of noncentrosymmetric chalcogenides, and
despite of adopting the same crystal structure type, its members show distinctively different …

Crystal Structures and Property Measurements of Rare Earth Magnesium Thiosilicates Synthesized via Flux Crystal Growth Utilizing the Boron Chalcogen Mixture …

AA King, LS Breton, G Morrison, MD Smith… - Inorganic …, 2023 - ACS Publications
Nine new rare earth magnesium-containing thiosilicates of the formula RE3Mg0. 5SiS7 (Ln=
Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er) were synthesized in an alkali halide flux using the boron …

Synthesis, Crystal Growth, Electronic Properties and Optical Properties of Y6IV2.5S14 (IV=Si, Ge)

Z Ye, S Bardelli, K Wu, A Sarkar… - … für anorganische und …, 2022 - Wiley Online Library
Two isostructural ternary acentric sulfides, Y6Si2. 5S14 (1) and Y6Ge2. 5S14 (2) were re‐
investigated to understand the origin of the chemical flexibility of RE6BxCyCh14 (RE= Y …

Quaternary rare-earth sulfides RE3M0. 5GeS7 (RE= La–Nd, Sm; M= Co, Ni) and Y3Pd0. 5SiS7

AK Iyer, W Yin, EJ Lee, X Lin, A Mar - Journal of Solid State Chemistry, 2017 - Elsevier
The two metal-deficient series of quaternary Ge-containing sulfides RE 3 M 0.5 GeS 7 (RE=
La–Nd, Sm; M= Co, Ni), as well as the related Si-containing sulfide Y 3 Pd 0.5 SiS 7, were …

Alkali-Metal Thiogermanates: Sodium Channels and Variations on the La3CuSiS7 Structure Type

A Choudhury, PK Dorhout - Inorganic Chemistry, 2015 - ACS Publications
Five new isotypic quaternary chalcogenides containing rare-earth metal atoms crystallizing
in the hexagonal noncentrosymmetric space group P 63 (No. 173) with the La3CuSiS7 …