Considering the recent rapid advancement of synthetic technologies promoted by visible
light in the last 15 years, the use of photocatalysts has been rightfully justified based on the …

Oxycarbenes have emerged as useful intermediates in synthetic chemistry. Compared to the
widely studied oxycarbene metal complexes bearing Group 6 metals, the synthetic and …

Fluorinated fused rings are challenging to construct from simple starting materials. Herein,
we report the first photocatalyzed cascade reactions of readily available cyclopropanols and …

Stereoselective cyclopropanation reaction of alkenes is usually achieved by metal
complexes via singlet‐metal‐carbene intermediates. However, previous transition‐metal …

Heterocyclic skeletons are commonly found in various bioactive molecules and
pharmaceutical compounds, making them crucial in areas such as medicinal chemistry …

Acylsilanes are emerging bench-stable reagents for the generation of electron-rich
oxycarbenes that are difficult to access with unstable diazo compounds. Herein, we report a …

Acylsilanes have been utilized in various transformations for the synthesis of functionalized
organosilicon derivatives due to their importance in medicinal and materials science. This …

Cyclopropanes are one of the most important strained rings existing in various
pharmaceutical products and secondary metabolites. They are also widely used in total …

Developing photo-induced cascade cyclization of alkene-tethered acylsilanes is
challenging, because acylsilanes are unstable under light irradiation. Herein, we report that …

Investigations into C− H amidation reactions catalysed by cationic half‐sandwich d6 metal
complexes revealed that the indenyl‐derived catalyst [Ind* RhCl2] 2 significantly accelerated …