Recyclable/degradable materials via the insertion of labile/cleavable bonds using a comonomer approach

C Lefay, Y Guillaneuf - Progress in Polymer Science, 2023 - Elsevier
Polymers have many advantages such as low weight, low cost, and, importantly, stability
under thermal, chemical, and mechanical stress. This stability, on the other hand, leads to …

Clip chemistry: diverse (bio)(macro) molecular and material function through breaking covalent bonds

P Shieh, MR Hill, W Zhang, SL Kristufek… - Chemical …, 2021 - ACS Publications
In the two decades since the introduction of the “click chemistry” concept, the toolbox of “click
reactions” has continually expanded, enabling chemists, materials scientists, and biologists …

Upcycling and catalytic degradation of plastic wastes

Q Hou, M Zhen, H Qian, Y Nie, X Bai, T Xia… - Cell Reports Physical …, 2021 - cell.com
Various recycling technologies have been developed to deal with plastic problems, but they
face considerable economic and technological challenges in practice. An attractive …

A versatile approach for the synthesis of degradable polymers via controlled ring-opening metathesis copolymerization

JD Feist, DC Lee, Y Xia - Nature Chemistry, 2022 - nature.com
Norbornene derivatives (NBEs) are common monomers for living ring-opening metathesis
polymerization and yield polymers with low dispersities and diverse functionalities …

Enol ethers are effective monomers for ring-opening metathesis polymerization: synthesis of degradable and depolymerizable poly (2, 3-dihydrofuran)

JD Feist, Y Xia - Journal of the American Chemical Society, 2019 - ACS Publications
Enol ethers are widely used as quenching reagents for Grubbs catalysts. However, we
report the surprisingly effective ring-opening metathesis polymerization (ROMP) of cyclic …

Geminal dimethyl substitution enables controlled polymerization of penicillamine-derived β-thiolactones and reversed depolymerization

W Xiong, W Chang, D Shi, L Yang, Z Tian, H Wang… - Chem, 2020 - cell.com
To access infinitely recyclable plastics, one appealing approach is to design
thermodynamically neutral systems based on dynamic covalent bond, the (de) …

Degradable polymers via olefin metathesis polymerization

H Sun, Y Liang, MP Thompson… - Progress in polymer …, 2021 - Elsevier
The development of degradable polymers has commanded significant attention over the
past half century. Approaches have predominantly relied on ring-opening polymerization of …

Backbone-photodegradable polymers by incorporating acylsilane monomers via ring-opening metathesis polymerization

B Huang, M Wei, E Vargo, Y Qian, T Xu… - Journal of the …, 2021 - ACS Publications
Materials capable of degradation upon exposure to light hold promise in a diverse range of
applications including biomedical devices and smart coatings. Despite the rapid access to …

Organocatalysis for versatile polymer degradation

P McKeown, M Kamran, MG Davidson, MD Jones… - Green …, 2020 - pubs.rsc.org
The use of a simple, cheap and effective organocatalyst, tetramethylammonium methyl
carbonate, has been exploited for the transesterification of a range of commercial polymer …

Elucidation of Substantial Differences in Ring-Opening Polymerization Outcomes from Subtle Variation of Glucose Carbonate-Based Monomer Substitution Patterns …

Y Shen, M Leng, Y Yang, SK Boopathi… - Journal of the …, 2023 - ACS Publications
The substituents present upon five-membered bicyclic glucose carbonate monomers were
found to greatly affect the reactivities and regioselectivities during ring-opening …