Binuclear and Mononuclear Aluminum Complexes as Quick and Controlled Initiators of Well‐ordered ROP of Cyclic Esters
Described herein is an efficient ring‐opening polymerization (ROP) of rac‐lactide and ϵ‐
caprolactone (ϵ‐CL) using novel bimetallic and monometallic aluminum complexes …
caprolactone (ϵ‐CL) using novel bimetallic and monometallic aluminum complexes …
Tri-coordinated zinc alkyl complexes with N^ S/Se coordination of imino-phosphanamidinate chalcogenide ligands as precursors for efficient hydroboration of nitriles …
A series of tri-coordinated zinc alkyl complexes with the general molecular formula [κ2NE-
{NHIRP (Ph)(E) N-Dipp} ZnEt][R= Dipp (2, 6-diisopropylphenyl), E= S (3a), Se (3b) and R …
{NHIRP (Ph)(E) N-Dipp} ZnEt][R= Dipp (2, 6-diisopropylphenyl), E= S (3a), Se (3b) and R …
Hydrosilylation of nitriles and tertiary amides using a zinc precursor
We report a competent and selective hydrosilylation of nitriles and tertiary amides catalyzed
by the readily available zinc bis (hexamethyldisilazide) under solvent-free and mild …
by the readily available zinc bis (hexamethyldisilazide) under solvent-free and mild …
Iron complexes supported by silyl-NHC chelate ligands: synthesis and use for double hydroboration of nitriles
T Komuro, K Hayasaka, K Takahashi, N Ishiwata… - Dalton …, 2024 - pubs.rsc.org
Iron complexes bearing new silyl-NHC bidentate ligands were synthesised by treating Fe3
(CO) 12 with a mixture of N-(hydrosilyl) methyl imidazolium salts and a base. These …
(CO) 12 with a mixture of N-(hydrosilyl) methyl imidazolium salts and a base. These …
Magnesium (II) complexes supported by indole-and pyrrole-containing Schiff-base ligands: syntheses, structures, and applications as precatalysts in the hydroboration …
M Wu, L Chen, X Yang, Y Li - New Journal of Chemistry, 2024 - pubs.rsc.org
The application of organometallic magnesium (II) compounds in the catalytic
dihydroboration of nitriles and hydroboration of alkynes has been reported. Five compounds …
dihydroboration of nitriles and hydroboration of alkynes has been reported. Five compounds …
Efficient cyanosilylation of carbonyls using a well-defined dimeric sodium complex
R Narvariya, H Karmakar, DA Kisan, I Paul… - Journal of …, 2024 - Elsevier
We present the synthesis and structural characterization of a novel dimeric sodium complex
with the chemical composition [{Ph 2 Si (H) PhN} Na (THF) 2] 2 (Na-1) supported by N, 1, 1 …
with the chemical composition [{Ph 2 Si (H) PhN} Na (THF) 2] 2 (Na-1) supported by N, 1, 1 …
Mononuclear Aluminum Complexes as Precursors for Cyanosilylation of Carbonyl Compounds
The synthesis, structural characterization, and catalytic application of two novel aluminum
complexes,[κ3ENSe−{Ph2P (E) N− C6H4− SePh} AlMe2][E= S (1) and Se (2)] supported by …
complexes,[κ3ENSe−{Ph2P (E) N− C6H4− SePh} AlMe2][E= S (1) and Se (2)] supported by …