Developments in the photophysics and photochemistry of actinide ions and their coordination compounds

LS Natrajan - Coordination Chemistry Reviews, 2012 - Elsevier
Actinide coordination chemistry is currently experiencing a renaissance, with the emergence
of exciting and less studied oxidation states, and previously unpredicted magnetic properties …

Ultrafast carrier dynamics in semiconductor nanowires

RP Prasankumar, PC Upadhya… - physica status solidi …, 2009 - Wiley Online Library
Semiconductor nanowires (NWs) are nanostructures with a number of novel optical and
electronic properties that offer great promise for applications in areas including …

Probing the 5f orbital contribution to the bonding in a U (V) ketimide complex

LA Seaman, G Wu, N Edelstein… - Journal of the …, 2012 - ACS Publications
Reaction of UCl4 with 5 equiv of Li (N CtBuPh) generates the homoleptic U (IV) ketimide
complex [Li (THF) 2][U (N CtBuPh) 5](1) in 71% yield. Similarly, reaction of UCl4 with 5 …

Emission spectroscopy of uranium (IV) compounds: a combined synthetic, spectroscopic and computational study

E Hashem, AN Swinburne, C Schulzke, RC Evans… - Rsc Advances, 2013 - pubs.rsc.org
Emission spectroscopy has been used for the first time in a spectroscopic study of a family of
uranium (IV) halide complexes in non-aqueous media. The room temperature electronic …

Phosphorano-Stabilized Carbene Complexes with Short Thorium (IV)–and Uranium (IV)–Carbon Bonds

P Rungthanaphatsophon, P Huang… - Organometallics, 2018 - ACS Publications
While no alkylidene complexes of the f elements are known, the use of phosphorano-
stabilized carbene complexes to produce short actinide–carbon bonds has been previously …

Lanthanides and actinides: annual survey of their organometallic chemistry covering the year 2008

FT Edelmann - Coordination Chemistry Reviews, 2011 - Elsevier
This review summarizes the progress in organo-f-element chemistry during the year 2008. A
continuing trend in organolanthanide research is a strong emphasis on applications of …

Synthesis and characterization of water stable uranyl (V) complexes

R Faizova, F Fadaei‐Tirani, AS Chauvin… - Angewandte …, 2021 - Wiley Online Library
The importance of uranyl (V)(UO2+) species associated with environmental and geologic
applications is becoming increasingly evident, but the tendency of the uranyl (V) cation to …

Comparative study of f-element electronic structure across a series of multimetallic actinide and lanthanoid-actinide complexes possessing redox-active bridging …

EJ Schelter, R Wu, JM Veauthier, ED Bauer… - Inorganic …, 2010 - ACS Publications
A comparative examination of the electronic interactions across a series of trimetallic
actinide and mixed lanthanide-actinide and lanthanum-actinide complexes is presented …

Photoluminescence of a Uranium (IV) Alkoxide Complex

LR Valerio, S Roy Chowdhury, R Lewis, KE Knowles… - JACS Au, 2024 - ACS Publications
In this report, we describe the photoluminescence of a homoleptic uranium (IV) alkoxide
complex. Excitation of [Li (THF)] 2 [UIV (O t Bu) 6] leads to the first example of …

The ketimide ligand is not just an inert spectator: Heteroallene insertion reactivity of an actinide–ketimide linkage in a thorium carbene amide ketimide complex

E Lu, W Lewis, AJ Blake… - Angewandte Chemie …, 2014 - Wiley Online Library
The ketimide anion R2C N− is an important class of chemically robust ligand that binds
strongly to metal ions and is considered ideal for supporting reactive metal fragments due to …