Electro-and solar-driven fuel synthesis with first row transition metal complexes
KE Dalle, J Warnan, JJ Leung, B Reuillard… - Chemical …, 2019 - ACS Publications
The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …
major step toward creating sustainable and scalable energy storage technologies. In the last …
Catalysts for nitrogen reduction to ammonia
SL Foster, SIP Bakovic, RD Duda, S Maheshwari… - Nature Catalysis, 2018 - nature.com
The production of synthetic ammonia remains dependent on the energy-and capital-
intensive Haber–Bosch process. Extensive research in molecular catalysis has …
intensive Haber–Bosch process. Extensive research in molecular catalysis has …
Single Mo atom supported on defective boron nitride monolayer as an efficient electrocatalyst for nitrogen fixation: a computational study
The production of ammonia (NH3) from molecular dinitrogen (N2) under mild conditions is
one of the most attractive and challenging processes in chemistry. Here by means of density …
one of the most attractive and challenging processes in chemistry. Here by means of density …
Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes
Nitrogen fixation, the six-electron/six-proton reduction of N2, to give NH3, is one of the most
challenging and important chemical transformations. Notwithstanding the barriers …
challenging and important chemical transformations. Notwithstanding the barriers …
Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism
The current industrial ammonia synthesis relies on Haber–Bosch process that is initiated by
the dissociative mechanism, in which the adsorbed N2 dissociates directly, and thus is …
the dissociative mechanism, in which the adsorbed N2 dissociates directly, and thus is …
Photocatalytic fixation of nitrogen to ammonia: state-of-the-art advancements and future prospects
The burgeoning development of ammonia (NH3) synthesis technology addresses the
urgency of food intake required to sustain the population growth of the last 100 years. To …
urgency of food intake required to sustain the population growth of the last 100 years. To …
Conversion of Dinitrogen to Ammonia by FeN3-Embedded Graphene
Nitrogen fixation is one of the most important issues but a long-standing challenge in
chemistry. Here, we propose FeN3-embedded graphene as the catalyst for nitrogen fixation …
chemistry. Here, we propose FeN3-embedded graphene as the catalyst for nitrogen fixation …
Promising prospects for 2D d 2–d 4 M 3 C 2 transition metal carbides (MXenes) in N 2 capture and conversion into ammonia
Density functional theory investigations of M3C2 transition metal carbides from the d2, d3,
and d4 series suggest promising N2 capture behaviour, displaying spontaneous …
and d4 series suggest promising N2 capture behaviour, displaying spontaneous …
Beyond ammonia: nitrogen–element bond forming reactions with coordinated dinitrogen
The functionalization of coordinated dinitrogen to form nitrogen–element bonds en route to
nitrogen-containing molecules is a long-standing challenge in chemical synthesis. The …
nitrogen-containing molecules is a long-standing challenge in chemical synthesis. The …
Comprehensive insights into synthetic nitrogen fixation assisted by molecular catalysts under ambient or mild conditions
Y Tanabe, Y Nishibayashi - Chemical Society Reviews, 2021 - pubs.rsc.org
N2 is fixed as NH3 industrially by the Haber–Bosch process under harsh conditions,
whereas biological nitrogen fixation is achieved under ambient conditions, which has …
whereas biological nitrogen fixation is achieved under ambient conditions, which has …