Conjugated metal–organic macrocycles: synthesis, characterization, and electrical conductivity

LB Zasada, L Guio, AA Kamin, D Dhakal… - Journal of the …, 2022 - ACS Publications
The dimensional reduction of solids into smaller fragments provides a route to achieve new
physical properties and gain deeper insight into the extended parent structures. Here, we …

Equilibration of imine‐linked polymers to hexagonal macrocycles driven by self‐assembly

AD Chavez, AM Evans, NC Flanders… - … A European Journal, 2018 - Wiley Online Library
Macrocycles based on directional bonding and dynamic covalent bond exchange can be
designed with specific pore shapes, sizes, and functionality. These systems retain many of …

Nitrogen‐Rich Conjugated Macrocycles: Synthesis, Conductivity, and Application in Electrochemical CO2 Capture

PH Le, A Liu, LB Zasada, J Geary… - Angewandte Chemie …, 2024 - Wiley Online Library
Here we report a series of nitrogen‐rich conjugated macrocycles that mimic the structure
and function of semiconducting 2D metal–organic and covalent organic frameworks while …

Controlling the crystal packing and morphology of metal–organic macrocycles through side-chain modification

LB Zasada, PH Le, AM Hill, RT Shafranek… - ACS Materials …, 2024 - ACS Publications
Supramolecular nanotubes constructed from the self-assembly of conjugated metal–organic
macrocycles provide a unique collection of materials properties, including solution …

Construction of Unsymmetrical Triphenylenes from Electron-Rich Biphenyls and Diaryliodonium Salts via Copper-Catalyzed Multiple C–H Arylation

Y Wu, W Zhang, Q Peng, CK Ran, BQ Wang, P Hu… - Organic …, 2018 - ACS Publications
An efficient protocol to synthesize unsymmetrical triphenylenes from electron-rich biphenyls
and diaryliodonium salts via Cu catalysis was developed. A variety of unsymmetrical …

Ultrasound-assisted one pot synthesis of polysubstituted meta-terphenyls using ring transformation strategy

SE Shetgaonkar, FV Singh - Synthetic Communications, 2019 - Taylor & Francis
An ultrasound-assisted rapid synthesis of meta-terphenyls 9 by the carbanion-induced ring
transformation reaction of 6-aryl-5-methyl-2 H-pyran-2-ones 7 with functionalized ketones 8 …

Self-Assembly of Nitrogen-Rich Conjugated Metal–Organic and Organic Macrocycles

P Le, L Zasada, J Geary, A Kamin, A Hill, D Xiao - 2023 - chemrxiv.org
Here we report the synthesis of nitrogen-rich conjugated metal–organic and organic
macrocycles that resemble truncated fragments of semiconducting 2D metal–organic and …

Conjugated Metal–Organic Macrocycles as Solution-Processable Semiconductors

L Porter-Zasada - 2024 - search.proquest.com
There has been recent widespread interest in porous self-assembling crystalline materials
for a wide variety of applications, but a striking lack of solution processability can greatly …

Synthetic Nanotubes via Acid-Mediated Macrocycle Assembly

MJ Strauss - 2021 - search.proquest.com
Nanotubes host a unique combination of structural precision, tunable interior environments,
and high-aspect ratios that are useful in many applications. Despite these desirable …