Chemical transformations that result in either the formation or cleavage of carbon–
heteroatom bonds are among the most important processes in the chemical sciences …

Carbide complexes remain a rare class of molecules. Their paucity does not reflect
exceptional instability but is rather due to the generally narrow scope of synthetic …

Data on the electronic structure and redox, magnetic, luminescent, nonlinear optical and
catalytic properties of tri-and tetranuclear molybdenum and tungsten chalcogenide clusters …

Although there are myriad binding modes of heterocumulenes to metal centers, the
monometallic κ2-ECE (E= O, S, NR) coordination mode has not been reported. Herein, the …

Open-shell compounds bearing metal–carbon triple bonds, such as carbides and carbynes,
are of significant interest as plausible intermediates in the reductive catenation of C1 …

Previous relativistic quantum-chemical predictions of unusually large 1H and 13C NMR
chemical shifts for ligand atoms directly bonded to a diamagnetic uranium (VI) center (P …

Transition-metal complexes featuring triple bonds to heavier Group 14 elements (Si, Ge, Sn,
and Pb), which have long been synthetic challenges in organometallic chemistry, have been …

The 13C and 29Si NMR signals of ligand atoms directly bonded to TlI or PbII heavy-element
centers are predicted to resonate at very high frequencies, up to 400 ppm for 13C and over …

The formation of linear hydrocarbon chains by sequential coupling of C1 units on the metal
surface is the central part of the Fischer–Tropsch (FT) synthesis. Organometallic complexes …

A detailed experimental and theoretical analysis is presented of unprecedented
molybdenum complexes featuring a linearly coordinated, multiply bonded silicon atom …