Helical polymers: synthesis, structures, and functions

E Yashima, K Maeda, H Iida, Y Furusho… - Chemical …, 2009 - ACS Publications
The helix is the central structural motif in biological macromolecules, such as DNA and
proteins, and is also the ubiquitous object in nature from microscopic to macroscopic points …

Dendron-mediated self-assembly, disassembly, and self-organization of complex systems

BM Rosen, CJ Wilson, DA Wilson, M Peterca… - Chemical …, 2009 - ACS Publications
1.1 Background Dendrimers and dendrons are architectural motifs synthesized by either
divergent or convergent iterative methods, and therefore, they provide monodisperse …

Single crystals of mechanically entwined helical covalent polymers

Y Hu, SJ Teat, W Gong, Z Zhou, Y Jin, H Chen, J Wu… - Nature Chemistry, 2021 - nature.com
Double helical conformation of polymer chains is widely observed in biomacromolecules
and plays an essential role in exerting their biological functions, such as molecular …

Supramolecular Assemblies from Poly (phenylacetylene) s

F Freire, E Quinoa, R Riguera - Chemical Reviews, 2016 - ACS Publications
The evolution of chemistry in the last 60 years can be illustrated by the introduction of just a
few new concepts. One is macromolecules,(1, 2) whose importance was recognized in the …

Towards high charge-carrier mobilities by rational design of the shape and periphery of discotics

X Feng, V Marcon, W Pisula, MR Hansen… - Nature materials, 2009 - nature.com
Discotic liquid crystals are a promising class of materials for molecular electronics thanks to
their self-organization and charge transporting properties. The best discotics so far are built …

Helical self-organizations and emerging functions in architectures, biological and synthetic macromolecules

V Percec, Q Xiao - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
Helical architectures including artwork and monuments, such us the Trajan's column from
Rome, were constructed as early as in the year 113 while the assemblies and the self …

Suzuki polycondensation: Polyarylenes à la carte

J Sakamoto, M Rehahn, G Wegner… - Macromolecular rapid …, 2009 - Wiley Online Library
This review draws a rather comprehensive picture of how Suzuki polycondensation was
discovered in 1989 and how it was subsequently developed into the most powerful …

Induced helical backbone conformations of self-organizable dendronized polymers

JG Rudick, V Percec - Accounts of chemical research, 2008 - ACS Publications
Control of function through the primary structure of a molecule presents a significant
challenge with valuable rewards for nanoscience. Dendritic building blocks encoded with …

Nanomechanical function from self-organizable dendronized helical polyphenylacetylenes

V Percec, JG Rudick, M Peterca… - Journal of the American …, 2008 - ACS Publications
Self-organizable dendronized helical polymers provide a suitable architecture for
constructing molecular nanomachines capable of expressing their motions at macroscopic …

Dissymmetric chiral poly (diphenylacetylene) s: secondary structure elucidation and dynamic luminescence

JJ Tarrío, R Rodríguez, B Fernández… - Angewandte …, 2022 - Wiley Online Library
The secondary structure of a dissymmetric and chiral poly (diphenylacetylene)(PDPA) is
elucidated by combining the data from NMR experiments (regioregular head to tail …