Microstructural and dynamical heterogeneities in ionic liquids

YL Wang, B Li, S Sarman, F Mocci, ZY Lu… - Chemical …, 2020 - ACS Publications
Ionic liquids (ILs) are a special category of molten salts solely composed of ions with varied
molecular symmetry and charge delocalization. The versatility in combining varied cation …

Gas–liquid interface of room-temperature ionic liquids

CS Santos, S Baldelli - Chemical Society Reviews, 2010 - pubs.rsc.org
The organization of ions at the interface of ionic liquids and the vacuum is an ideal system to
test new ideas and concepts on the interfacial chemistry of electrolyte systems in the limit of …

Surface tensions of imidazolium based ionic liquids: Anion, cation, temperature and water effect

MG Freire, PJ Carvalho, AM Fernandes… - Journal of Colloid and …, 2007 - Elsevier
This work addresses the experimental measurements of the surface tension of eight
imidazolium based ionic liquids (ILs) and their dependence with the temperature (288–353 …

Density and surface tension of ionic liquids

C Kolbeck, J Lehmann, KRJ Lovelock… - The Journal of …, 2010 - ACS Publications
We measured the density and surface tension of 9 bis [(trifluoromethyl) sulfonyl] imide
([Tf2N]−)-based and 12 1-methyl-3-octylimidazolium ([C8C1Im]+)-based ionic liquids (ILs) …

Vibrational spectra of imidazolium tetrafluoroborate ionic liquids

NE Heimer, RE Del Sesto, Z Meng, JS Wilkes… - Journal of molecular …, 2006 - Elsevier
The Raman and infrared spectra of a series of 1-alkyl-3-methylimidazolium tetrafluoroborate
ionic liquids ([C2-4MIM][BF4]) are reported and analyzed using Density Functional Theory …

Molecular dynamics simulation of the electrochemical interface between a graphite surface and the ionic liquid [BMIM][PF 6]

SA Kislenko, IS Samoylov, RH Amirov - Physical Chemistry Chemical …, 2009 - pubs.rsc.org
The structure of the electrical double layer in the ionic liquid l-butyl-3-methylimidazolium
hexafluorophosphate ([BMIM][PF6]) near a basal plane of graphite was investigated by …

Structures of ionic liquids with different anions studied by infrared vibration spectroscopy

Y Jeon, J Sung, C Seo, H Lim, H Cheong… - The Journal of …, 2008 - ACS Publications
We investigated the structures of ionic liquids (1-butyl-3-methylimidazolium iodide [BMIM][I]
and 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF4]) and their aqueous mixtures …

Ionic liquid clusters: structure, formation mechanism, and effect on the behavior of ionic liquids

S Chen, S Zhang, X Liu, J Wang, J Wang… - Physical Chemistry …, 2014 - pubs.rsc.org
The microstructure of ionic liquids (ILs) has attracted much attention due to their relevance in
physiochemical properties and behavior of ILs. The existence of clusters (or …

Structural studies of the phase, aggregation and surface behaviour of 1-alkyl-3-methylimidazolium halide+ water mixtures

I Goodchild, L Collier, SL Millar, I Prokeš… - Journal of colloid and …, 2007 - Elsevier
The surface, phase and aggregation behaviour of mixtures of 1-alkyl-3-methylimidazolium
halide,[Cnmim] X, where n is the alkyl chain length, with water has been explored using a …

Surface layering in ionic liquids: an X-ray reflectivity study

E Sloutskin, BM Ocko, L Tamam… - Journal of the …, 2005 - ACS Publications
The surface structure and thermodynamics of two ionic liquids, based on the 1-alkyl-3-
methylimidazolium cations, were studied by X-ray reflectivity and surface tensiometry. A …