Rare earth starting materials and methodologies for synthetic chemistry
F Ortu - Chemical Reviews, 2022 - ACS Publications
The number of rare earth (RE) starting materials used in synthesis is staggering, ranging
from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl …
from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl …
Advances in structurally characterized lanthanide alkoxide, aryloxide, and silyloxide compounds
TJ Boyle, LAM Ottley - Chemical reviews, 2008 - ACS Publications
Often referred to as the “rare earths”, the lanthanide (Ln) elements have gained increased
attention over the past few decades. This has been due to the development of better …
attention over the past few decades. This has been due to the development of better …
Developments in the coordination chemistry of europium (II)
Recent advances in the coordination chemistry of Eu2+ are reviewed. Common synthetic
routes for generating discrete Eu2+‐containing complexes reported since 2000 are …
routes for generating discrete Eu2+‐containing complexes reported since 2000 are …
Enhancing the Value of Free Metals in the Synthesis of Lanthanoid Formamidinates: Is a Co‐oxidant Needed?
Abstract Treatment of N, N′‐bis (aryl) formamidines (ArFormH), N, N′‐bis (2, 6‐
difluorophenyl) formamidine (DFFormH) or N, N′‐bis (2, 6‐diisopropylphenyl) formamidine …
difluorophenyl) formamidine (DFFormH) or N, N′‐bis (2, 6‐diisopropylphenyl) formamidine …
Synthesis of Bis(2,6-Diadamantyl Aryloxide) Ln(II) Complexes of Samarium, Europium, and Ytterbium and Their Ln(III) Precursors
LM Anderson-Sanchez, JW Ziller, WJ Evans - Inorganic Chemistry, 2024 - ACS Publications
The syntheses of Ln (II) bis (aryloxide) complexes of Sm, Eu, and Yb have been examined
with the bulky aryloxide ligand (OC6H2-2, 6-Ad2-4-t Bu) 1–[(OAr*) 1–; Ad= 1-adamantyl] …
with the bulky aryloxide ligand (OC6H2-2, 6-Ad2-4-t Bu) 1–[(OAr*) 1–; Ad= 1-adamantyl] …
Analogy of the Coordination Chemistry of Alkaline Earth Metal and Lanthanide Ln2+ Ions: The Isostructural Zoo of Mixed Metal Cages [IM(OtBu)4{Li(thf)}4(OH)] (M=Ca, Sr, Ba, Eu), [MM′6 …
W Maudez, M Meuwly… - Chemistry–A European …, 2007 - Wiley Online Library
As previously shown, alkali and alkaline earth metal iodides in nonaqueous, aprotic solvents
behave like transition metal halides, forming cis‐and trans‐dihalides with various neutral O …
behave like transition metal halides, forming cis‐and trans‐dihalides with various neutral O …
Synthesis, structure and oxidation of new ytterbium (II) bis (phenolate) compounds and their catalytic activity towards ε-caprolactone
EE Delbridge, DT Dugah, CR Nelson, BW Skelton… - Dalton …, 2007 - pubs.rsc.org
Two ytterbium (II) bis (phenolate) complexes,[LRYb] where R= NMe21 and OMe 2, have
been synthesized and characterized, with 1 being structurally defined to be a dimeric …
been synthesized and characterized, with 1 being structurally defined to be a dimeric …
Distinct Reaction Pathways of Peralkylated LnIIAlIII Heterobimetallic Complexes with Substituted Phenols
HM Sommerfeldt, C Meermann, KW Törnroos… - Inorganic …, 2008 - ACS Publications
The protonolysis reaction of heterobimetallic peralkylated complexes [Ln (AlR4) 2] n (Ln=
Sm, Yb; R= Me, Et) with 2 equiv of HOC6H2 t Bu2-2, 6-Me-4 affords the bis …
Sm, Yb; R= Me, Et) with 2 equiv of HOC6H2 t Bu2-2, 6-Me-4 affords the bis …
Gas-phase reactions of lanthanide cations with alcohols
JM Carretas, J Marçalo, AP de Matos - International Journal of Mass …, 2004 - Elsevier
The gas-phase reactions of the lanthanide series cations Ln+ (Ln= La–Lu, except Pm) with
methanol, ethanol, and 2-propanol were studied by Fourier transform ion cyclotron …
methanol, ethanol, and 2-propanol were studied by Fourier transform ion cyclotron …
Synthesis and energetics of Na, K, Rb and Cs salts by reaction with 1, 2-ethanediol and 1, 4-butanediol
LMC Silva, PG Rosado, JB Branco, MA Antunes… - The Journal of Chemical …, 2017 - Elsevier
The study of direct reactions of Na, K, Rb and Cs with 1, 2-ethanediol and with 1, 4-
butanediol was undertaken as well as the reactions of Na and K with 1, 2-ethanediol by an …
butanediol was undertaken as well as the reactions of Na and K with 1, 2-ethanediol by an …