Metal-containing clusters have attracted increasing attention over the past 2–3 decades.
This intense interest can be attributed to the fact that these discrete metal aggregates, whose …

Molecular magnetism, though distinctly a field within chemistry, encompasses much more
than synthesis and has strong links with other disciplines across the physical sciences …

Magnetic refrigerants with a large magnetocaloric effect (MCE) in a wide temperature range
and low magnetic ordering temperature (T o) in the sub-kelvin temperature region are not …

Gigantic coordination molecules assembled from a large number of metal ions and organic
ligands are structurally and functionally challenging to characterize. Here we show that a …

Clusters showing a giant magnetocaloric effect (MCE) are of interest as molecular coolants
for magnetic refrigeration. Herein, we report two heterometallic clusters, denoted as Gd 152 …

The discovered giant clusters are always highly symmetric owing to the spontaneous
assembly of one or two basic units. Herein we report the Gd44Co28 crown and Gd95Co60 …

It is a meaningful and challenging work for structural and synthetic chemists to isolate nano-
sized high-nuclearity cluster-molecules. In this work, two largest hetero-metallic nano …

Progress in the synthesis, design, and characterisation of single-molecule magnets (SMMs)
has expanded dramatically from curiosity driven beginnings to molecules that retain …

We show that molecular spin qudits provide an ideal platform to simulate the quantum
dynamics of photon fields strongly interacting with matter. The basic unit of the proposed …

We employ quantum Monte Carlo to obtain chemically accurate vertical and adiabatic
excitation energies, and equilibrium excited-state structures for the small, yet challenging …