Main group metal polymerisation catalysts

E Fazekas, PA Lowy, MA Rahman… - Chemical Society …, 2022 - pubs.rsc.org
With sustainability at the forefront of current polymerisation research, the typically earth-
abundant, inexpensive and low-toxicity main group metals are attractive candidates for …

A quest for polycarbonates provided via sustainable epoxide/CO 2 copolymerization processes

SJ Poland, DJ Darensbourg - Green Chemistry, 2017 - pubs.rsc.org
The present review highlights advances in the copolymerization of carbon dioxide (CO2)
and epoxides (oxiranes) to produce polycarbonates. Specifically, focus has been given to …

Copolymerization of carbon dioxide and epoxides by metal coordination complexes

CM Kozak, K Ambrose, TS Anderson - Coordination Chemistry Reviews, 2018 - Elsevier
The catalytic copolymerization of CO 2 with epoxides to give polycarbonates was discovered
nearly 50 years ago. The last 10 years have been particularly exciting for the development …

Free-radical/cationic hybrid UV-curable silicone resin for age-resistant coatings

S Huang, H Huang, X Liu, H Xiang - Industrial & Engineering …, 2024 - ACS Publications
To achieve the unique advantages of silicone resin and the free-radical/cationic hybrid UV-
curing mechanism, a free-radical/cationic hybrid UV-curable silicone resin (MTQ-TQ-T) is …

Terpenes and terpenoids: building blocks to produce biopolymers

MEG Mosquera, G Jiménez, V Tabernero… - Sustainable …, 2021 - mdpi.com
Polymers are essential materials in our daily life. The synthesis of value-added polymers is
mainly performed from fossil fuel-derived monomers. However, the adoption of the circular …

Salen-type aluminum and zinc complexes as two-faced Janus compounds: contribution to molecular sensing and polymerization catalysis

M Strianese, D Pappalardo, M Mazzeo… - Dalton …, 2020 - pubs.rsc.org
The aim of the present review is to highlight the most recent achievements in different fields
of application of salen-based zinc and aluminum complexes. More specifically this article …

Use of limonene epoxides and derivatives as promising monomers for biobased polymers

E Louisy, V Khodyrieva, S Olivero, V Michelet… - …, 2022 - Wiley Online Library
Abstract (R)‐Limonene, a renewable terpene, and its epoxidized derivatives, ie limonene
epoxides, have prompted growing attention over the last decade as building blocks for the …

Well-defined and structurally diverse aromatic alternating polyesters synthesized by simple phosphazene catalysis

H Li, H Luo, J Zhao, G Zhang - Macromolecules, 2018 - ACS Publications
Alcohol-initiated ring-opening alternating copolymerization (ROAP) of phthalic anhydride
(PA) and a variety of mono-, di-, and trisubstituted epoxides has been performed with a weak …

Fully alternating and regioselective ring-opening copolymerization of phthalic anhydride with epoxides using highly active metal-free Lewis pairs as a catalyst

A Kummari, S Pappuru, D Chakraborty - Polymer Chemistry, 2018 - pubs.rsc.org
A recent study has been directed to the design of metal-free Lewis pair catalysts for ring-
opening alternating copolymerization (ROAP) reactions to enhance both activity and …

Progress in metal-free cooperative catalysis for the ring-opening copolymerization of cyclic anhydrides and epoxides

S Pappuru, D Chakraborty - European Polymer Journal, 2019 - Elsevier
Recent progress in the design of metal-free Lewis pair catalysts indicates a bright future for
the synthesis of various polyesters with broad applications. In the present review, we attempt …